pH Flashcards

1
Q

what is a proton?

A

H+ ion

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2
Q

what is pH?

A

logarithmic scale which measures the concentration of H+ ions in a solution

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3
Q

how is pH calculated?

A

-log10[H+]

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4
Q

how is [H] from pH calculated?

A

10-pH

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5
Q

what is the assumption of strong acids and bases when calculating pH?

A

they dissociate fully into H+ and OH- ions

base/acid conc = [ion]

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6
Q

calculate the pH for [H] 0.01

A

-log(0.01 = 2

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7
Q

calculate the pH for [H] 16.2x10-13

A

-log(16.2x10-13 = 11.8

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8
Q

calculate the pH for [H] 0.000251

A

-log(0.000251 = 3.6

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9
Q

calculate [H] for pH 3.12

A

10(-3.12 = 7.59x10-4

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10
Q

calculate [H] for pH 6.09

A

10(-6.09 = 8.13x10-7

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11
Q

calculate [H] for pH 12.01

A

10(-12.01 = 9.77x10-13

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12
Q

what is a high pH value in terms of ion concentration?

A
  • 14
  • low conc of H+ ions
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13
Q

what is a low pH value in terms of ion concentration?

A
  • 0
  • high conc of H+ ions
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14
Q

what is the strength of an acid?

A

the extent of its dissociation into H+ and A- ions when in aq solution

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15
Q

describe strong acids

A
  • good proton donors
  • dissociate completely
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16
Q

describe weak acids

A
  • poor proton donors
  • partially dissociate
    (reversible arrow in equation)
17
Q

where does equilibrium lie when a weak acid dissociates?

A

left
- only partially dissociates

18
Q

where does equilibrium lie when a strong acid dissociates?

A

right
- fully dissociates

19
Q

write the general equation for dissociation of a weak acid

A

HA <=> H+ + A-

20
Q

state the general Ka expression

A

[H+] [A-] / [HA]
[products]/[reactants]

21
Q

what does Ka show?

A

extent of acid dissociation

22
Q

what does a large value of Ka show?

A

shift of equilibrium to the right
greater dissociation = greater acid strength

23
Q

how is pKa calculated?

A

-logKa

24
Q

what is pKa?

A

a way of measuring the strength of an acid similar to pH

25
Q

what does a low pKa tell you?

A

stronger acid