Periodicity Flashcards

1
Q

In metallic bonding delocalised outer electrons produces…

A

An electrostatic force of attraction between the positive metal ions and the negative delocalised electrons.

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2
Q

What is a covalent bond ?

A

A shared pair of electrons electrostatically attracted to the positive nuclei of two non-metal atoms.

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3
Q

How do the atoms achieve a stable outer electron arrangement (a noble gas arrangement) ?

A

By sharing electrons.

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4
Q

Most of the discrete covalent molecules are…

A

Diatomic

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5
Q

There are also some larger covalent molecular elements:

A

Phosphorus (P4)
Sulfur (S8)
Fullerenes (C60)

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6
Q

What are covalent networks ?

A

Large, rigid three dimensional arrangements of atoms held together by strong covalent bonds.

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7
Q

Why do covalent networks have high melting points ?

A

Because they only contain strong covalent bonds.

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8
Q

Example of covalent network

A

Carbon in the forms of diamond and graphite.

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9
Q

Which elements exist as single unattached particles ?

A

Group 0 elements (noble gases) including helium, neon and argon.

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10
Q

Noble gases are…

A

Stable atoms

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11
Q

Noble gases do not usually…

A

Form molecules with other atoms.

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12
Q

Monatomic elements have…

A

Low MPts and BPts as weak forces of attraction between the atoms.

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13
Q

What is the first ionisation energy ?

A

The energy involved in removing one mole of electrons from one mole of atoms in the gaseous state.

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14
Q

The second ionisation energy is…

A

The energy required to remove a second mole of electrons.

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15
Q

The third ionisation energy shows a massive increase because…

A

It requires an electron to be removed from Magnesium’s second energy level.

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16
Q

As you go across the periodic table the ionisation energy…

A

Increases due to an increase in nuclear charge having a greater pull on the electrons and therefore more energy is required to remove electrons.

17
Q

As you go down a group in the periodic table the ionisation energy…

A

Decreases due to the screening effect of the outer electrons from the nucleus and so the attraction is weaker and they are removed more easily.

18
Q

As you go across the periodic table the covalent radius…

A

Decreases due to there being more electrons in the outer energy level and more protons in the nucleus which results in an increased nuclear charge

19
Q

As you go down a group in the periodic table the covalent radius…

A

Increases due to the screening effect of the filled inner electron levels, these electron screen the outer electrons from the nuclear charge.

20
Q

What is electronegativity ?

A

A measure of an atom’s attraction for the electrons in a bond.

21
Q

As you go across the periodic table electronegativity…

A

Increases due to the atoms having a greater nuclear charge and a smaller covalent radius which allows the nucleus to attract bonding electrons more strongly.

22
Q

As you go down a group in the periodic table electronegativity…

A

Decreases due to extra energy levels and increased covalent radius which keep the bonding electrons further away from the nucleus.