Periodicity Flashcards
what happens to shielding as you go across a period?
stays the same - electron shells remain the same
what is periodicity?
trends in properties across a PERIOD shown across the next PERIOD
what happens to atomic radius as you go across a period?
1) Nuclear charge increases
2) Shielding stays the same
Therefore, force of attraction between nucleus and electrons increases
what is first ionisation energy?
Enthalpy change for this process: give example
E.g Na(g) -> Na+ + e-
what happens to 1st ionisation energy as you go across a period?
Increases because nuclear force increases but shielding remain the same therefore the strength of attraction between the nucleus and the outermost electron increases, requiring more energy to overcome
how do you measure atomic radius?
internuclear distance/2
what is key when judging 1st ionisation energy?
the POSITION of the outer electron - what sub-shell is it in
and
electrons in the orbitals - is there any repulsion?
what is a metallic bond?
an electrostatic force of attraction between positive ions and delocalised electrons
what is the difference between intermolecular and intramolecular forces?
inter = between molecules intra = within molecules, between atoms in molecules