Periodicity Flashcards

1
Q

Define Periodicity

A

A repeating trend in properties across each period.

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2
Q

What the left hand side block called?

A

S- BLOCK

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3
Q

Whats the middle block called?

A

D- block.

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4
Q

Whats the right hand side block called?

A

P- Block

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5
Q

Define first ionisation energy

A

The energy required to remove one electron from each atom in 1 mole of gaseous atoms to form 1 mole of gaseous 1+ ions.

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6
Q

What is the general trend in ionisation energy down a group.

A

The increased nuclear charge is outweighed by increased atomic radius and increased electron shielding so attraction between nucleus and outer Most electrons is weaker.
Therefore ionisation energy decreases down a group.

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7
Q

What is the general trend in ionisation energy across a period?

A

Ionisation energy increases across a period as increased nuclear charge, but shielding remains constant, leading to a decrease in atomic radius and a stronger attraction between the nucleus and outer electrons.

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8
Q

What is the reason for the dip in ionisation energy from group 2 to 3.

A

As the electron is being lost from a higher sub level (3p sub level instead of 3s) which has higher energy, Therefore the electron is lost more easily so smaller ionisation energy.

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9
Q

What is the reason for the dip in ionisation energy from group 5 to 6.

A

As the electron is being lost from an orbital with a paired electron, the electrons repel one another so one of them is lost more easily so it has a lower ionisation energy.

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10
Q

What substances in period 2 and 3 will have giant covalent lattices?

A

Boron, Carbon and silicon.

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11
Q

Why do substances that have giant covalent lattices have high melting and boiling points.

A

As we are breaking the strong covalent bonds between the ATOMS.

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12
Q

Why do diamond and silicone not conduct electricity?

A

As all four outer shell electrons are involved in covalent bonding.
so electrons cannot move and are not available for conducting electricity.

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13
Q

Why do graphite and graphene conduct electricity?

A

one delocalised electron per cation, the delocalised electrons are able to move therefore conduct electricity.

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14
Q

Why are compounds with giant covalent structure unable to conduct electricity?

A

As the strong covalent bonds between the atoms are hard to break.

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15
Q

Why are compound with ionic structure soluble in water?

A

electrostatic attraction between polar water molecules and ions break up the lattice.

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16
Q

Why do molecules with simple molecular structure not conduct?

A

as all the outer electrons are localised in bonds, unable to move.

17
Q

Why are there big jumps in ionisation energy?

A

Electrons in inner shells experience much greater attraction than those in outer shells therefore the attraction is greater.