Periodicity Flashcards

1
Q

what is the covalent radius

A

half the distance between the nuclei of 2 of its bonded atoms

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2
Q

what happens to the size of atoms as you go across a period

A

they decrease

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3
Q

why does the size of an atom decrease as you go across a period

A

as you go across a period the positive charge on the nucleus increases. The shells or energy levels of electrons are strongly attracted to the nucleus

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4
Q

what happens to the size of an atom as you go down a group

A

there is another electron shell so the size of the atom increases

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5
Q

what is the first ionisation energy of an element

A

the first ionisation energy of an element is the energy required to remove one mole of electrons from one mole of an atom in the gaseous state

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6
Q

what happens to the first ionisation energy as you go along a period

A

it increases

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7
Q

what happens for the first ionisation energy as you go down a group

A

it decreases

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8
Q

why does the ionisation energy increase going along a period

A

due to the increases nuclear charge across a period, outer electrons are held more tightly to the nucleus so more energy if required to remove them

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9
Q

why does the first ionisation energy decrease going down a group

A

going down a group the atomic size increases due to there being more energy shells. Inner electron shells shield the outer electrons reducing the attraction of the positive nuclear charge

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10
Q

why is the second ionisation energy always greater then the first

A

in the second ionisation energy negative electrons are being removed from positive ions, rather than neutral atoms. In the positive ion has a greater traction for the electron so more energy is required to remove the second mole of electrons

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11
Q

why is the second ionisation energy of K (2,8,8,1) greater then the second ionisation energy of Mg (2,8,2)

A

The second ionisation energy of K involves removing an electron from a stable electron arrangement, this requires a lot of energy. Whereas the second ionisation energy of Mg involve removing an electron from an unstable electron arrangement this requires less energy

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