PERIODIC TRENDS Flashcards
Ionization Energy (IE):
Energy required to remove an electron.
Increases across a period (left to right) because of stronger nuclear attraction.
Decreases down a group because of increased shielding and atomic radius.
Electronegativity
Ability of an atom to attract electrons in a bond.
Increases across a period due to increasing nuclear charge.
Decreases down a group because of greater atomic size and shielding.
Atomic Radius:
Distance from the nucleus to the outermost electron.
Decreases across a period due to stronger nuclear pull.
Increases down a group due to the addition of electron shells.
Shielding Effect:
Inner electron shells block outer electrons from nuclear attraction.
Increases down a group as more shells are added.
Remains constant across a period, as electrons are added to the same energy level
Metallic Character:
Increases down a group (easier electron loss).
Decreases across a period (stronger nuclear attraction).
Reactivity Trends
Metals
Metals: More reactive down a group (easier electron loss) and increases as you move to the left of the periodic table
Reactivity Trends
Non-Metals
Non-Metals: More reactive up a group (stronger electron attraction).
Effective Nuclear Charge
= protons – shielding (inner) electrons
Increases across a period (more protons, but similar shielding).
stays roughly the same down a group
why do atoms get smaller across the periodic table
Atomic radius decreases across a period because increasing protons (+ charge) pull electrons closer. Since shielding remains nearly constant, effective nuclear charge (Z_eff) increases, drawing valence electrons inward and shrinking the atom.
Why does effective nuclear charge increase from left to right?
Effective nuclear charge increases from left to right across the periodic table because of the increasing atomic charge and constant shielding effect. Due of a similar number of shielding electrons across a period, the valence electrons are pulled more tightly to the nucleus. This creates a smaller atomic radius, higher ionization energy, and higher net positive charge on the atom.