Periodic Table Trends Flashcards
Define Electronegativity
Electronegativity is the ability of an atom to attract electrons. Electronegativity increases across the periodic table.
What is changing as we go across and down the periodic table?
- The number of protons (+) in the nucleus
- The distance between nucleus and valence electrons
- Shielding from inner electron shells
Define Ionisation (IE)
Ionisation is the amount of energy required to remove one valence electron from a mole of atoms when they are in a gas state. Unit kJ mol-1
Across a row (IE)…
Ionisation energy increases. This is due to the increasing electrostatic attraction across a row
Down a group (IE)
Ionisation energy decreases. This is due to the decreasing electrostatic attraction down a group
Define Atomic radius
Atomic radius is the measurement of the size of the atom. The distance between the nucleus and the outermost electrons. If an atom is bigger, it will have smaller electronegativity.
Across a row (Atomic radius)
Atomic radius decreases. This is due to the increasing electrostatic attraction across a row, electrons are pulled in closer
Down a group (Atomic radius)
Atomic radius increases. This is due to the decreasing electrostatic attraction down a group, electrons are not pulled in as close
Define Ionic radius
Ionic radius is the measurement of the size of the ion. The distance between the nucleus and the outermost electrons.
Positive ions (ie Metals)
- Lose electrons from their outer shell
- Therefore, fewer electron shells so the distance from the nucleus of the outer shell and shielding decreases
- A positive ion has a smaller radius than its atom
Negative ions (ie Non-metals)
- Gain electrons onto their outer shell
- Therefore, increased repulsion between the increased number of electrons
- Energy shells and proton numbers stay the same
- A negative ion has a larger radius than its atom