Period Three Elements Flashcards

1
Q

How does Na react with water? Give an equation.

A
  • Sodium reacts with cold water.
  • It shows effervescence on the surface.
  • 2Na(s) + 2H2O(l) —> 2NaOH(aq) + H2(g)
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2
Q

How does Mg react with cold water and with steam? Give 2 equations

A
  • Magnesium reacts very slowly with cold water to form the hydroxide but reacts more readily with steam to form the oxide.
  • Mg + 2H2O —> Mg(OH)2 + H2
  • Mg + H2O —> MgO + H2
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3
Q

What are the observations for the period 3 elements reacting with oxygen? (Up to S)

A
  • Na burns with a yellow flame to produce a white solid.
  • Mg, Al, Si, P burns with a white flame to give a white solid and smoke.
  • S burns with a blue flame to form an acidic choking gas.
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4
Q

Give an equation for the reaction of sodium and oxygen?

A

4Na(s) + O2(g) —> 2Na2O(s)

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5
Q

Give an equation for the reaction of Mg and O2?

A

2Mg(s) + O2(g) —> 2MgO(s)

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6
Q

Give an equation for the reaction of Al and O2?

A

4Al(s) + 3O2(s) —> 2Al2O3(s)

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7
Q

Give an equation for the reaction of Si and O2?

A

Si(s) + O2(g) —> SiO2(s)

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8
Q

Give an equation for the reaction of phosphorous with oxygen?

A

4P(s) + 5O2(g) —> P4O10(s)

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9
Q

Give an equation for the reaction of S and O2?

A

S(s) + O2(g) —> SO2(g)

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10
Q

Why is Na stored under oil and P under water?

A

Prevent the element coming into contact with and therefore reacting with oxygen?

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11
Q

How does the period three metal ionic oxide sodium oxide react with water? Give an equation and suggest a pH value.

A

Sodium oxide:
- vigorous exoteric reaction
- Na2O(s) + H2O(l) —> 2Na+(aq) + 2OH-(aq)
- pH = 13/14

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12
Q

How does the period three metal ionic oxide magnesium oxide react with water? Give an equation and suggest a pH value.

A

Magnesium oxide:
- MgO(s) + H2O(l) —> Mg(OH)2(s)
- pH = 9

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13
Q

How does the period three metal ionic oxide aluminium oxide react with water? Give an equation and suggest a pH value.

A

Aluminium oxide:
- Does not dissolve in water due to high strength of the lattice
- pH = 7

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14
Q

Why does Mg(OH)2 have lower pH than NaOH in solution?

A

Mg(OH)2 is only slightly soluble in water as it’s lattice is stronger.
Hence, it dissolved less. There are fewer free OH- ions produced.
Lower pH.

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15
Q

How does SiO2 react with water? What is the pH of the products?

A

It does not dissolve in water due to it’s macromolecular structure.
pH = 7

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16
Q

How does the period three non-metal oxide phosphorus oxide react with water?

A

P4O10(s) + 6H2O(l) —> 4H3PO4(aq)
pH = 0

17
Q

How do the period three non-metal sulphur oxides react with water?

A

Acidic solutions formed
SO2(g) + H2O(l) —> H2SO3(aq)
SO3(g) + H2O(l) —> H2SO4(aq)

18
Q

Give the equation for the reaction of sodium oxide and hydrochloric acid?

A

Na2O(s) + 2HCL(aq) —> 2NaCl(aq) + H2O(l)

19
Q

Give the equation for the reaction of magnesium oxide and hydrochloric acid?

A

MgO(s) + 2HCl(aq) —> MgCl2(aq) + H2O(l)

20
Q

Give an equation for the equation of sodium hydroxide with sulfuric acid?

A

Na2O(s) + H2SO4(aq) —> Na2SO4(aq) + H2O(l)

21
Q

Give an equation for the reaction of aluminium oxide and sulfuric acid?

A

Al2O3(s) + 3H2SO4(aq) —> Al2(SO4)3(aq) + 3H2O(l)

22
Q

Give an equation for the reaction between Al2O3 and NaOH?

A

Al2O3(s) + 2NaOH(aq) + 3H2O(l) —> 2NaAl(OH)4

23
Q

Give an equation for the reaction of SiO2 with NaOH?

A

2NaOH + SiO2 —> Na2SiO3 + H2O

24
Q

Give an equation for the reaction of phosphorous oxide and sodium hydroxide?

A

P4O10(s) + 12NaOH(aq) —> 4Na3PO4(aq) + 6H2O(l)

25
Give an equation for the reaction of P4O10 and Na2O
P4O10 + 6Na2O —> 4Na3PO4
26
Give the equation for the reaction of SO2 and SO3 with NaOH?
- SO2(g) + 2NaOH(aq) —>Na2SO3(aq) + H2O(l) - SO3(g) + 2NaOH(aq) —> Na2SO4(aq) + H2O(l)
27
How do you experimentally prove that a compound contains ions?
- melt the solids - show they conduct electricity
28
Explain why Na/Mg oxide forms an alkaline solution when they react with water?
- Na/Mg oxide contains O2- ions - These O2- ions react with water forming OH- ions - The O2- is said to be hydrolysed to OH- - O2- + H2O —> 2OH-
29
Write two equations to demonstrate the amphoteric nature of Al2O3 (2m)
Basic: - Al2O3 + HCl —> AlCl3 + H2O Acidic: - Al2O3 + 2NaOH + 3H2O —> 2Na[Al(OH)4]
30
What are the observations for when Mg reacts with steam?
- Bright white flame. - White solid formed.