Period 3 elements Flashcards

1
Q

What is atomic radius?

A

the distance between the nucleus and the outermost electrons of an atom

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2
Q

What does atomic radius do across the period? and why does it do this?

A

Decreases

-the nuclear charge is increasing meaning there’s greater attraction between the nucleus and out electrons drawing them closer together

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3
Q

What is ionic radius

A

the distance between the nucleus and the outermost electron of an ion

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4
Q

What does ionic radius do for cations across a period? and why?

A

It decreases

-they have lost their valency electron which causes them to be smaller hence less shielding effect

-as nuclear charge increases the electrostatic attraction also increases

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5
Q

What does ionic radius do for anions across a period? and why?

A

increases

-they are gaining electrons and are larger so the distance between the nucleus and the outermost electron continues increasing cause weaker electrostatic attraction towards the nucleus

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6
Q

What is the trend in melting and boiling points across period 3?

A

-From Na to Al the m.p and b.p increases due to an increase in metallic bonding
(there’s a stronger electrostatic attraction between the metal cations and the delocalised electrons)

-Si has the highest m.p and b.p because it is a macromolecule that has a giant covalent lattice structure
(more energy is required to break the bonds)

-From P4 to Cl2 the m.p and b.p is dependant on the intermolecular forces/ VDW forces
(the greater the surface area the more the Vdw forces, so S8 has the higher m.p and b.p)

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7
Q

What is the trend for electrical conductivity across period 3?

A

From Na to Al it increases and then decreases for other elements
(it increases because the number of delocalised electrons increases so more carriers available for electricity)

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8
Q

What is the equation of sodium oxide and what products are produced?

A

2Na (s) + 1/2O2 (g) ——> Na2O (s)
bright yellow flame
white solid formed

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9
Q

What is the equation of magnesium oxide and what products are produced

A

2Mg (s) + O2 (g) ——> 2MgO (s)
bright white flame
white solid formed

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10
Q

What is the equation of Aluminium oxide and what products are produced

A

4Al (s) + 3O2 (g) ——> 2Al2O3 (s)
bright white flame
white solid formed

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11
Q

What is the equation of Silicon oxide and what products are produced

A

Si (s) + O2 (g) ——–> SiO2 (s)
bright White sparkles
white solid formed

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12
Q

What is the equation of Phosphorus oxide and what products are produced

A

4P (s) + 5O2 (g) ——-> P4O10 (s)
yellow or white flame
white clouds formed

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13
Q

What is the equation of Sulphur oxide and what products are produced

A

S (s) + O2 (g) ——-> SO2 (s)
blue flame
toxic fumes produced

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14
Q

What is the reaction of sodium with chlorine?

A

2Na + Cl2 ——-> 2NaCl
bright orange flame
white solid formed
vigorous reaction

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15
Q

What is the reaction of Magnesium with chlorine?

A

Mg + Cl2 ——> MgCl2
bright white flame
white solid formed

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16
Q

What is the reaction of Aluminium with chlorine?

A

2Al + 3Cl2 ——-> 2AlCl3
pale yellow aluminium chloride

17
Q

What is the reaction of Sodium with water?

A

2Na +2H2O ——> 2NaOH +H2
-undergoes an exothermic reaction with cold water
- hydrogen is produced
-colourless solution of sodium hydroxide

18
Q

What is the reaction of Magnesium with water?

A

Mg + H2O ——-> Mg(OH)2 + H2
-reacts slowly
- bubbles of hydrogen are produced -thin layer of magnesium hydroxide forms on magnesium

19
Q

What is the acid/base nature of Na2O and MgO?

A

basic

20
Q

What is the acid/base nature of Al2O3?

A

amphoteric

21
Q

What is the acid/base nature of SiO2, P4O10 and SO2/SO3?

A

acidic

22
Q

What is the chemical bonding and structure present in Na2O, MgO and Al2O3?

A

ionic bonding
giant ionic

23
Q

What is the chemical bonding and structure present in SiO2, P4O10 and SO2/SO3?

A

-covalent bonding
-giant covalent for SiO
-simple molecular for P4O10 and SO2/SO3