Period 3 and their oxides Flashcards
comparison of melting points of magnesium and sodium
magnesium has a higher melting point as has 2+ charge so has a higher charge density
what is sodium metal like
quite a soft, silvery metal which tarnishes quickly in air
what is magnesium metal like
harder than sodium and is often seen a ribbon
equation for sodium reacting with water
2Na (s) + 2H2O (l) → 2NaOH (aq) + H2 (g)
how does sodium react with water
-vigorous, exothermic reaction
-sodium floats on surface of the water fizzing rapidly and melting as a result of the heat produced during the reaction
solution formed when sodium reacts with water
-sodium hydroxide
-pH of 13-14 so is very alkaline
oxidation state of sodium when it reacts with water
-changes form 0 in elemental state
- +1 in NaOH
equation of magnesium in cold water
Mg (s) + 2H2O (l) → Mg(OH)2 (aq) + H2 (g)
reaction of magnesium with cold water
-extremely slow reaction
solution formed when magnesium reacts with cold water
-Magnesium hydroxide forms
-pH 10 as is only partly soluble
-key component in milk of magnesia
oxidation state when magnesium reacts with cold water
-changes from 0 in elemental state
-+2 in magnesium hydroxide
equation for reaction of heated magnesium with steam
Mg (s) + H2O (g) → MgO (s) + H2 (g)
observations of magnesium and steam
-burns with a bright, white flame
products of hot magnesium reacting with steam
magnesium oxide and hydrogen gas
oxidation states of hot magnesium reacting with steam
-oxidation state changes from 0 to +2 in magnesium oxide
comparison of magnesium reacting with water and steam
-reaction with steam is much faster than reaction with cold water
-magnesium oxide and hydrogen gas are produced when reacting with steam
-magnesium hydroxide and hydrogen gas are produced when reacting with cold water
sodium oxide formula
Na2O
magnesium oxide formula
MgO
aluminium oxide formula
Al2O3
silicon oxide formula
SiO2
phosphorus oxide formula
P4O10
sulfur dioxide formula
SO2
reaction of sodium and oxygen
4Na (s) + O2 (g) → 2Na2O (s)
reaction of magnesium and oxygen
2Mg (s) + O2 (g) → 2MgO (s)
reaction of aluminum and oxygen
4Al (s) + 3O2 (g) → 2Al2O3 (s)
reaction of silicon and oxygen
Si (s) + O2 (g)→ SiO2 (s)
reaction of phosphorus and oxygen
4P (s) + 5O2 (g) → P4O10 (s)
reaction of sulfur and oxygen
S (s) + O2 (g) → SO2 (g)
reaction condition to produce Na2O
heated
reaction condition to produce MgO
heated
reaction condition to produce Al2O3
powdered Al
reaction condition to produce SiO2
powdered Si and heat strongly
reaction conditions to produce P4O10
heated
reaction condition to produce SO2
powdered S is heated
reaction to produce Na2O
vigorously
reaction to produce MgO
vigorously
reaction to produce Al2O3
fast
reaction to produce SiO2
slowly
reaction to produce P4O10
vigorously
reaction to produce SO2
gently
flame from Na
bright yellow flame
flame from Mg
bright white flame
flame from Al
bright white flame
flame from Si
bright white sparkles
flame from P
yellow or white flame
flame from S
blue flame
product observation from Na2O
white solid
product observation from MgO
white solid
product observation from Al2O3
white powder
product observation from SiO2
white powder
product observation from P4O10
white clouds
product observation from SO2
toxic fumes
how does sulfur form sulphur trioxide
catalyst must be used and a very high temperature
2S (s) + 3O2 (g) → 2SO3 (g)
what type of oxides are sodium, magnesium and aluminium oxides
ionic oxides
type of oxide is silicon oxide
macromolecular (giant covalent)
what type of oxides are phosphorus and sulfur oxides
simple molecular
adding water to Na2O
reacts and forms hydroxide ions in solution with a typical pH of 13
adding water to MgO
slightly soluble, dissolved oxide forms a few hydroxide ions in solution, typical pH of 8
adding water to Al2O3
insoluble but amphoteric
adding water to SiO2
insoluble but acidic
adding water to P4O10
acidic recats and gives H+ ions in solution, typical pH of 2
adding water to SO2
acidic, reacts and forms weak acid H2So3 with a few H+ ions in solution, typical pH of 3
adding water to SO3
acidic, reacts and forms string acid H2SO4 with H+ ions in solution, typical pH os 1
how does covalent character change across period 3
increases
how does ionic character change across period 3
decreases