PChem Flashcards
Boyle’s Law
pV = constant, at constant n, T
Charles’s Law
V = constant•T, at constant n, p
p = constant•T, at constant n, V
Raising the T increases the speed of the molecules, thus more collisions with the walls occur.
Avogadro’s Principal
V = constant•n, at constant T, p
Molecular explanation of Boyle’s Law
When the V is reduced by 50% the number of molecular collisions doubles, thus the force exerted by the gas on the walls of the container doubles
Molecular explanation of Charles’s Law
Raising the T of a gas increases the average speed of the molecules.
Therefore they collide with the walls more frequently and with a greater impact.
Hess’s Law
The standard reaction enthalpy is the sum of the values for the individual reactions into which the overall reaction may be divided