Past Boards Shuffled Flashcards
Number of carbon atoms in olvanil
C26 H43 NO3
Who discovered x ray?
Wilhelm Conrad Roentgen
Method of oxidatively cleaning alkenes or alkynes using ozone, a reactive allotrope of oxygen
Ozonolysis
Center of atom
Nucleus
Blanket of pollutants
Primary, secondary
Note: BLANKET (Base-Line Network of the EPA Tasmania
Pollutant produced from coal and petroleum
CO2 and SO2
Nearest layer of atmosphere from earth’s surface
Troposphere
It is a method of N-terminal residue analysis of a peptide chain in which the terminal amino acid reacts with phenyl isothiocyanate to form a substituted thiourea which is then hydrolyzed mildly with acid to remove the N terminal residue as a phenylthiohydantoin for identification
Edman degradation
Chemical reaction of sunlight, nitrogen oxides and volatile organic compounds in the atmosphere
Photochemical Smog
Six Criteria Pollutants
POLSCN Particulate matter Ozone Lead Sulfur dioxide Carbon Monoxide Nitrogen Oxides
Chemical formula and molecular weight of 11 tetradecenyl Acetate
C16 H30 O2
MW 254.414
What is the product when ethanoyl chloride is reacted with propanol?
Propyl ethanoate
Reaction: Ethanoyl chloride + propanol-> propyl ethanoate + hydrogen chloride
What is the primary use of ethylene?
Ripening of fruits
What are the contaminants which BTEX refers to?
Benzene, Toluene, Ethyl Benzene, Xylene isomers
What is the heat of reaction when ethylene is hydrogenated to ethane?
🔼H=-296 kj
Where is an enzyme CAPSAICIN commonly found?
SHU (Scoville Heat Units)
What is the other name of bulk temperature?
Mixing up temperature
What is the method that Wolher do to break the vital force theory in nature?
Heating of NH4Cl with AgCN to form Urea(NH2)2CO
What law is the PRC Modernization Act?
RA 8981 -PRC Modernization Act of 2000 (Repealed PD 223)
Arrange the following substance in terms of increasing melting points
Palmitic
Oleic
Stearic
Oleic< Palmitic < Stearic
What is the common form of Nitro-glycerol?
Nitroglycerin
Definition of Polar Bond
Bonding of heteronuclear molecules with UNEQUAL sharing of electrons
Which of the ff functional group is the most polar and least polar? ROH RNH2 RCOOH C TRIPLE BOND C C-C
Most Polar : ROH
Least Polar : C-C and C triple bond C
What is the range of melting point of fatty acids?
-11 to 70
What is true about alkyl halides and ordinary HC’s?
Higher boiling point, lower density of alkyl halides compared to ordinary
Dehydrogenation of propane
Propene
Base structure of aspirin is
Benzene
Reaction of benzene where the product is phenol
Hydration
Which of the following is used as sacrificial lamb for Fe?
Zinc
A subatomic particle with the same mass as an electron but of a positive charge
Positron
Which is true about ionic radius of positively charged and negatively charged?
Positively charged ions : have SMALLER radius then neutral
Negatively charged ions : have longer radius then neutral
Which has larger Ionic radii , positively charged or negatively charged or neutral?
->0>+
Constitutional isomers: which is a true statement?
Same MW, same molecular, same connectivity, same physical properties
A metabolic pathway that results in the generation of glucose from non-carbohydrate carbon substrates such as lactate, glycerol, and glucogenic amino acids
Gluconeogenesis
What can be formed from starch?
Glucose
Cloth wrap in Jesus Christ, what happened after subjecting to C-H dating?
There is a result and the cloth seemed to be younger
Use of zinc oxide
Sunblock
Who discovered radioactivity?
Henri Becquerel
Property exhibited by certain types of matter of emitting energy and subatomic particles spontaneously. It is the essence, an attribute of individual nuclei.
Radioactivity
Who discovered vulcanized rubber?
Charles Goodyear
What is the common characteristic of Citric Acid and Malic Acid?
- Both are intermediate of the Citric Acid Cycle (Kreb’s Cycle)
- Both are responsible for sour taste of some fruits
Effect in mass number and atomic number of alpha emission
(-4,-2)
Nucleus of an atom splits into smaller parts. Produces free neutrons and gamma photons and releases a very large amount of energy
Nuclear fission
Isotopes have
- similar chemical properties (same no of electrons)
- different physical properties (different no of neutrons)
- different radioactive properties (depending on nuclear structure)
Atomic mass unit is defined as
Exactly 1/12 of the mass of a carbon-12 atom
What is the common use of EDTA (Ethylenediamene tetraacetic acid)?
Chelating or sequestering agent for metal cations
Also known as sodium calcium edetate
Is it possible to have a pH equal to 0?
Yes
Chemical formula of Aspirin
In handbook : CH3CO2C6H4CO2H(C9H8O4)
What element has the symbol Tb?
Terbium
Most stable isotope of Boron
Boron-10
Most penetrating radiation
Gamma
Molecular formula of sucrose
C12H12O11
Person behind carbon dating
Willard Libby
Which of the following decrease in entropy
Melting of ice
What is the solid part of the earth’s crust
Lithosphere
In IR spectroscopic analysis of solids, the sample is mixed with special, inert mineral oil to have a very thick suspension before being placed in the spectrometer
Nujol mull process
What is the sign convention of enthalpy during endothermic reaction?
+
What is the polymer used for printing and coating?
Epoxy Polymer
Another name for taurine
2-aminoethanesulfonate acid (C2H7NO3S) pKa 9.06
Which float or sink in water? Balsa wood Ethelyne glycol Table salt Ethanol
Float
Sink
Sink
Float
3 alphe emissions and 2 beta emissions of Rn-222
Pb-210
It is the heterolytic reaction in which a nucleophile (basic, electron rich reagent) attacks the nucleus of a carbon in another molecule, resulting in substitution.
Nucleophilic substitution
Which of the following compounds is a synthetic dye?
Alizarin
At constant temperature, amount of gas dissolved in a given type and volume of liquid is directly proportional to the partial pressure of that gas in equilibrium with that liquid
Henry’s Law
In quantum mechanics, it is a principle which states that values of particular pairs of observables cannot be determined simultaneously with arbitrarily high precision.
Heisenberg uncertainty principle
Used for measuring the density of milk
Lactomer
What amino acid has sulfur containing group?
Methionine, cysteine, homocysteine, taurine