part 2 Flashcards
enthalpy of formation
heat energy transferred when 1 mole of a substance is formed in its standard state from its elements in their standard states
standard conditions
298 K
1 atm
aliphatic hydrocarbons
no benzene rings
aromatic hydrocarbons
contains benzene rings
where do Pi bonds of occour
carbon to carbon double bonds
where do sigma bonds occur and why are they stronger
occur at single bonds, stronger as closer to nuclei
What happens in catalytic cracking?
larger hydrocarbon molecules are heated with a catalyst and undergo thermal decomposition to form shorter hydrocarbons
structural isomers definition
same molecular formula but different structural formula
values different from experimental results
heat loss to surroundings
unable to maintain standard conditions
incomplete combustion
values different from data books
bond enthalpies are averages
data book values are from elements all in their gaseous states