part 2 Flashcards

1
Q

enthalpy of formation

A

heat energy transferred when 1 mole of a substance is formed in its standard state from its elements in their standard states

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2
Q

standard conditions

A

298 K

1 atm

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3
Q

aliphatic hydrocarbons

A

no benzene rings

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4
Q

aromatic hydrocarbons

A

contains benzene rings

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5
Q

where do Pi bonds of occour

A

carbon to carbon double bonds

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6
Q

where do sigma bonds occur and why are they stronger

A

occur at single bonds, stronger as closer to nuclei

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7
Q

What happens in catalytic cracking?

A

larger hydrocarbon molecules are heated with a catalyst and undergo thermal decomposition to form shorter hydrocarbons

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8
Q

structural isomers definition

A

same molecular formula but different structural formula

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9
Q

values different from experimental results

A

heat loss to surroundings
unable to maintain standard conditions
incomplete combustion

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10
Q

values different from data books

A

bond enthalpies are averages

data book values are from elements all in their gaseous states

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