Palm Cards Flashcards
Define a Laminate
Laminate is a product
made by bonding
together two or more thin
layers (plies or laminae)
of materials. Most
common composites
employed in aircraft
industry are polymer
matrix laminates.
Driving factors for composite selection
Weight, strength, resistance to environmental effects, performance under temperature extremes, resistance to damage and fatigue. Assembly costs
Role of both the fibers and the matrix in a complete composite.
Fibers: Oriented for principal stress/es in order to carry the major load/s
Matrix: Transmits load to/from fiber. Shapes and protects.
At what orientation relative to fiber direction is the composite strongest?
Along fiber direction
Polymer Matrix Composites (PMCs) vs Metals
- Properties are not uniform in all directions
- Strength and stiffness can be tailored to meet loads
- Possess a greater variety of mechanical properties
- Have poor through the thickness (short transverse) strength
- Are usually laid up in two dimensional form, while metals
may be used in billets, bars, forgings, castings, etc. - Have greater sensitivity to environmental heat and moisture
- Possess greater resistance to fatigue damage
- Damage propagates through delamination rather than
through-the-thickness cracks
PMC Advantages Over Metals
- Light weight
- Resistance to corrosion
- High resistance to fatigue damage
Reduced machining
Tapered sections and compound contours easily
accomplished
Strength and stiffness can be tailored
Reduced number of assemblies and reduced fastener count
when co-cured or co-consolidation is used
Absorb radar microwaves (stealth capability)
Near zero thermal expansion reduces thermal problems in
outer space applications
PMC Disadvantages Over Metals
Composite Materials are expensive
Less historical data and established design allowables
Corrosion problems can result from improper coupling with
metals, especially when graphite is used (sealing is
essential)
Degradation of structural properties under temperature
extremes and wet conditions
Poor energy absorption and impact damage resistance
May require lightning protection
Expensive and complicated inspection methods
Reliable detection of substandard bonds is difficult
Internal nature of defects makes damage assessment
difficult
Reasons for Lower-than-Expected Usage of Composites
High Cost of raw materials and manufacture
High Cost of Certification
Low Resistance to Impact
Damage and transverse cracking
Limited applicability at high temperatures
Advancement in aluminium alloys
(improved toughness,
fatigue resistance and corrosion resistance)
Development of new light weight alloys (Al-Li)
Low cost aerospace grade castings, mechanical alloying and
super-plastic forming, diffusion bonding
Advanced joining techniques for metals (laser and friction
welding, automated riveting
Different Types of Polymers
- Polymer Matrix Composites
- Metal Matrix Composites
- Ceramic Matrix Composites
- Carbon Carbon Composites
Hybrid Metal/PMC Composites
Types of Matrix Reinforcements
- Continuous Fibers made from light elements (C, B, Si, etc)
- Whiskers: Ultra strong, stiff, short fibers made up of single crystals
- Particulates: Mainly ceramic, to improve toughness of brittle matrices
- Nanotubes
Types of strengths provided by a matrix
Transverse, Shear, Compressive
Service temperatures of the different composite types
PMC: Less than 300 deg
MMC: Less than 650 deg
CMC: Less than 1400 deg
C/C: Greater than 1400 deg
Overview of PMC Benefits
Light weight, high performance
fibers in organic polymer matrices
Usually processed at low temperatures and pressures.
reasonably low cost.
Easier to machine, mould and fabricate
Limited high temperature applications
Susceptible to environmental degradation
Includes thermosets and thermoplastics.
MMCs compared to PMCs
Higher temperature resistance.
High melting point
High ductility and toughness
Higher dimensional stability (low CTEs)
Mostly heavier than PMCs
Costly, complex and limited fabrication techniques
Problems with thermal coefficient mismatch and poor
interfacial bonding between reinforcements and matrices
Susceptible to corrosion
Types of MMCs
Aluminium Metal
Magnesium and Copper
Titanium Alloys Intermetallics
Types of MMC Reinforcements
Continuous Fibers
Whiskers
Particulates
Manufacturing Methods for MMCs
Rapid liquid metal processes such as squeeze casting
Powder metallurgy processes based on heating
compacted metal powders to just below their melting
points to consolidate them (Hot Isostatic Press)
Some conventional metal working techniques for
particulate MMCs
Super plastic forming
Diffusion bonding (for Ti matrix systems)
Additive manufacturing.
Types of ceramic composites, and their operating temperatures
- Glass ceramics (up to 500deg)
- Oxides (?)
- Nitrides (up to 1400 deg)
- Carbides (Over 1400 deg)
Overview of ceramic composites
Ceramic matrices reinforced with continuous fibres,
whiskers or particulates
High temperature applications in gas turbine engines and
high temperature airframe/space structures
Ceramics are brittle and subject to microcracking at high temperatures
Hence reinforcing fibres with high strength and stiffness
that have chemical stability and resistance to oxidation at
high temperatures as well as matching CTEs are required
Hence it is common to use similar materials for both
reinforcement and matrix such as SiC/SiC and alumina
fibres in alumina matrix.
Features of C/C Composites
C/C has the best structural properties (specific
strength, specific stiffness, creep resistance, at the highest
operating temperatures (over 20,000 C) of all materials
Further it has no significant chemical or thermal expansion
compatibility problems
Its greatest disadvantage is susceptibility to oxidation at
high temperatures
Hence C/C is the main candidate for use in rocket nosecones, nozzles, and leading edges on hypersonic wings.
Advantages of Hybrid Metal/PMC Composites
Combines the advantages of metals (such as high
resistance to low velocity impact damage) with the advantages of
PMCs (such as high fatigue life).
They typically consist of thin sheets of metal (usually Aluminium)
bonded together with a fibre reinforced adhesive.
Much higher fatigue lives than
monolithic alloys and greater impact resistance than PMCs
They have lower densities than aluminium, higher post yield
strength and higher damping capacity
Disadvantages of Hybrid Metal/PMC Composites
Higher sensitivity to blunt notches,
lower elastic modulus than monolithic aluminium
Possibility of earlier
crack initiation, and
high cost.
Types of Fiber Metal Laminates
ARALL, GLARE
Explain how fiber form of a material relates to the probability of a defect being present
Elements of low atomic number have strong directional inter-atomic bonds.
The strong bonding inhibits plastic flow, so they are very
sensitive to sub-microscopic flaws.
These materials can achieve very high strengths when made
into fibers due to the probability of a flaw being present
being proportional to the volume of the materials for a given length.
However, for the same reason, they also become very sensitive to flaws, exhibiting a much higher variability in
strength compared to bulk materials.
Explain why fibers have high strength
The probability of a flaw being present is proportional to the
volume of the materials for a given length (and fibres have very
low cross sectional area).
Flaws can be minimized by proper manufacturing and coating procedures
Drawing and spinning impose high strains along the fibre axis
produces a more favourable orientation of crystal structure
High cooling rate or rapid molecular deposition produces ultrafine grained structures with much higher properties.
Explain the process used to manufacture glass fibers
Glass is first melted at temps between 12500 and 14000 C
Flows into an electrically heated alloy
bushing which contains a large number of holes at its base
The glass drops emerging from the holes are drawn into fibres at speeds of up to 50 m/s
They are cooled by a water spray and coated with a “size” by a rolling applicator
Finally the fibres are combined into a strand (of 52, 102 or
204 fibres) and wound on to a take-up spool
How do the properties of glass fiber differ from those of the bulk material?
The cooling rate experienced by the fibres is very high
(greater than 10,0000 C per sec)
Hence the fibre structure is different from that of bulk glass,
resulting in a higher tensile strength but lower
elastic modulus and chemical resistance
Outline how flaws affect glass fibres
Glass fibres, being essentially monolithic, linearly elastic brittle
materials, are very sensitive to flaws in the form of sub-microscopic inclusions and cracks
Commercial fibres are particularly prone to abrasion against
other fibres, resulting in a reduction in strength of up to 20% compared to pristine fibres
Humid environments reduce the strength of glass fibres under
sustained loading due to adsorption of moisture on to the surface causing “static fatigue”
Individual fibre strength is reduced by about 50% in a PMC, but
the bundling of the fibres overcomes this effect.
Define the two types of glass fiber
- E-Glass:
Calcium Alumino-Borosilicate used for
electrical applications due to its higher
electrical resistivity. - S Glass:
Magnesium Alumino-Silicate, used for
structural applications due to its higher
strength and low cost
What is ‘Size’, and why is it used?
Consists of a lubricant, binders such as starch and
polyvinyl alcohol (to hold filaments together) and primers to
improve adhesion between fibres and matrices.
Reduces damage caused by friction upon fibres.
Carbon Fiber:
- Why is it used
- What Types
- What is it made from
- High specific strength and stiffness
- High Modulus, High
Strength, Intermediate Modulus - Organic precursor materials (PAN and Pitch) by a
process of carbonization.
What is PAN
PolyAcryloNitrile is an acrylic textile fibre
How is PAN manufactured:
By wet or dry spinning of the polymer or co-polymer, and then stretching.
Stretching of fibres during spin reduces the diameter, aligns more molecular chains along the length, increasing stiffness
How is carbon fiber manufactured from PAN?
Stage 1 – Stabilisation: PAN is first stabilised in air at about 2500C
by oxidation to form a thermally stable ladder polymer, with a high
glass transition temperature (Tg).
Stage 2 – Carbonisation: Removal of N, O and H in an inert nitrogen atmosphere at 1200-16000C. Fibres develop full strength at 1500-16000C. Basal planes align along the fibre axis, but remain as extended 2D ribbons.
Stage 3 – Graphitisation: Final heat treatment at 1500-25000C in an
inert atmosphere (Argon), wherein basal layers grow and coalesce along the fibre direction, to provide higher E (up to 380 GPa) at the cost of lower strain capability (0.7%) and strength.
What is Pitch?
What are its advantages and drawbacks?
Precursor made of organic compounds
Cheap but poor mechanical properties
Low compression, shear and tensile properties.
High electrical and thermal conductivity.
No tension required to develop molecular orientation (unlike PAN).
How is Pitch manufactured into carbon fiber
Stage 1 – Isotropic to Mesophase Pitch: Isotropic pitch is
subjected to prolonged heating in an inert atmosphere at 400-
4500C to form a liquid crystal phase (mesophase) which is meltspun into fibre form
Stage 2 – Cross linking: To reduce relaxation, the pitch fibres are
cross linked by heating for a short time at 3000C in atmosphere containing O2.
Stage 3 – Pre Carbonisation
Stage 4 – Carbonisation
Stage 5 – Graphitisation
Benefits and drawbacks of Boron fibers.
How are they made
Very hard
Difficult to machine
Chemical vapor deposition
Properties of Aramid fibers
Superior Specific Properties: Higher specific properties compared to glass fibers.
Tensile Properties: Good tensile properties up to 400°C.
Compressive Strength: Poor compressive strength limits applications.
Energy Absorption: High energy absorption during fracture. High strain-to-failure.
Applications: Used in ballistic protection and engine containment rings
Anisotropic Properties: Strong covalent bonds within chains and weak hydrogen bonds between chains result in anisotropic properties.
Non-linear Compression: Highly non-linear under compression due to kink band formation from in-phase compressive buckling of fibrils.
Thermal Stability: Strength reduces by about 20% at 180°C, with rapid decline thereafter.
Hygroscopic Nature: Absorbs moisture (around 4% at 60% relative humidity for Kevlar 49), but tensile strength remains largely unaffected.
Creep Characteristics: Significant short-term creep, negligible long-term creep.
UV Degradation: Susceptible to UV degradation, but protected in PMCs by resin matrix.
Properties of polyethylene fibres
Tough
Operate best under 100 deg temps
Poor creep behavior
Low compressive strengths due to kink band formation
Specific strengths comparable to aramids.
List the types of dry fiber forms
- Mats
- Woven Fabrics
- Warns
- Tows
- Rovings
- Braided Fabrics
- Non-Crimp Fabrics
- Tapes
- 3D textile preforms
Function of the matrix
Provides shape
Holds the fibres together
Transfers load in and out of fibres
Separates the fibres to prevent failure from
adjacent fibres
Protects fibres from environmental damage
Determines “matrix dominated” properties:
- Longitudinal compressive strength
- Transverse tensile strength
- Intra and interlaminar shear strength
Service temps for different matrix types
- Low temp thermosets (epoxies, polyesters, vinyl esters, phenolic resins)
= 100 - 150 deg - Medium temp thermosets (Bismaleimides)
= Up to 230 deg - High temp thermosets (Polyimides)
= Up to 300 deg
Properties of an epoxy resin
- Excellent chemical and mechanical properties at low temps
- Low viscosity during curing, enabling easier forming
- Low shrinkage
- Good fiber adhesion
- Tg increases with increasing cure temperature
Limitations of epoxy resins
Low toughness, and sensitive to impact damage
Limited temp range
Absorbs moisture
Sensitive to UV exposure
High cost compared to polyesters
Less convenient curing compared to polyesters
List the additives used in epoxy resins, and describe their effects
- Diluents
Added to reduce viscosity
before cure - Flexibilizers
Added to reduce elastic modulus
and increase elongation to failure - Toughening agents Increase fracture toughness
and reduce crack propagation rates - Inert fillers, such as hollow glass microspheres:
Added to alter density, resin flow and
effective modulus
List and describe the mechanisms through which an epoxy resin can be toughened.
Formation of a solid solution with a more ductile polymer
Precipitation of elastomeric second phase
Development of interpenetrating polymer networks
The inclusion of elastomeric second phase can be achieved by
adding an elastomer (rubber) to form a copolymer with the
base resin which then precipitates out upon curing to form a
dispersed second phase
Adding a very fine powder to form a dispersion