PAG 3 Enthalpy determination Flashcards

1
Q

outline how to find enthalpy of a reaction

A

pour water into a beaker using a measuring cylinder and record the water added

record the initial temperature of the water using a thermometer

add methanol to a spirit burner and weigh the burner

light the burner and heat the beaker using the spirit burner

after 3 mins blow out the spirit burner

record the final temperature of the water

record the final mass of the spirit burner

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2
Q

diagram for enthalpy determination

A
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3
Q

why may the value for enthalpy of combustion calculated be LESS EXOTHERMIC than the recorded values?

A

non standard conditions
incomplete combustion
heat loss to surroundings
evaporation of methanol from wick

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4
Q

how could the practical be modified to obtain a more accurate value for enthalpy of combustion?

A

use a draught screen to prevent heat loss

insulate the beaker to prevent heat loss

burn the chemical in oxygen to ensure complete combustion

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5
Q

why may the value for enthalpy of combustion calculated be MORE EXOTHERMIC than the recorded values?

A

smaller moles were calculated which means a larger enthalpy change of combustion was calculated

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6
Q

why is it not possible to measure the enthalpy change of formation for a hydrocarbon directly?

A

the reaction of hydrogen and carbon leads to the production of many different hydrocarbons

hydrogen and carbon cannot react in standard conditions

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7
Q

what happens if you double the temperature in an enthalpy determination practical?

A
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