P3 - Thermal Physics Flashcards
Properties of particles in solids
- The molecules are very close together and arranged in a regular pattern
- The molecules vibrate about fixed positions
Properties of particles in liquids
- The molecules are still close together (no gaps) but are no longer arranged in a regular pattern
- The molecules are able to slide past each other
Properties of particles in gases
- The molecules are widely separated
- The molecules move about randomly at high speeds
Describe the strength of bonds in solids
- molecules held in place by strong intermolecular forces
- these prevent molecules from moving: rigid shape and fixed volume
Describe the strength of bonds in liquids
- have enough energy to make their bonds weaker
- bonds are still there but they no longer hold the molecules in place
- molecules can move around (slide) so liquid can flow
Describe the strength of bonds in gases
- The molecules have broken the bonds between them: they are widely separated with no long-range forces binding them together
- the molecules are able to move freely and so the gas can flow freely - Because of the large spaces between the molecules the gas can easily be compressed and is also able to expand
Formula for pressure
force / area (F/A)
How is temperature related to pressure?
- The hotter the gas, the faster the molecules move because of an increase in kinetic energy
- As the molecules move around, they collide with the surface of the walls of their container and each other
- Each collision applies a force across the surface area of the walls
- pressure is exerted on those walls
Momentum formula
mass x velocity
How does momentum change relate to pressure?
- When molecules collide against a wall, they bounce off, changing their momentum (right = +mv; left = -mv)
- collisions every second, resulting in a large change in momentum each second
- change in momentum each second results in a force being exerted against the wall: F = (mv-mu)/t
- Pressure exerted by the gas is equal to this force divided by the area of the wall
Brownian motion
The erratic/random motion of small particles when observed through a microscope (colloidal particles)
Kinetic Molecular Theory
The theory that all matter is composed of particles (atoms and molecules) moving constantly in random directions
What is brownian motion caused by?
- By molecules in the gas (or liquid) colliding at high speeds with the small particles
- particles change their speed and directions randomly, each time they are struck by a molecule
How can massive particles be moved by small molecules?
The small, fast-moving molecules surround the large particles in large quantities which causes them to be moved
Evaporation
A change in state of a liquid to a gas that can happen at any temperature from the surface of a liquid
What are the differences between evaporation and boiling?
- Change of state: liquid to gas (evaporation and boiling)
- Temperature: at any temp. (evaporation); only at the boiling point (boiling)
- Where: the surface (evaporation); throughout the liquid (boiling)
How is energy transferred during evaporation?
- Evaporation occurs when more energetic molecules near the surface of the liquid have enough energy to escape
- when this happens energy is lost from the liquid: - The average energy of the remaining molecules decreases: the temperature of the remaining liquid will also decrease
Factors affecting evaporation (3)
- Temperature of the liquid: at higher temperatures, more molecules have enough energy to escape
- The surface area of the liquid: with greater surface area there will be more area from which the molecules can escape
- The movement of air across the surface of the liquid: presence of a draft can help to remove less energetic molecules
How can evaporation cool things down?
If an object is in contact with an evaporating liquid, as the liquid cools the solid will cool as well
What factors increase pressure?
- Increasing the temperature of a gas (whilst keeping its volume fixed)
- Decreasing the volume of a gas (whilst keeping the temperature fixed)
Boyle’s law
If a gas has an original pressure, P1, and volume, V1, then its final pressure and volume (P2 and V2) will be given by the relationship: P1V1 = P2V2
Boyle’s law formula
P1 x V1 = P2 x V2
Thermistor
A resistor whose resistance depends on the temperature of the thermistor
Thermocouple
A thermoelectric device for measuring temperature, consisting of two wires of different metals connected at two points
- a voltage being developed between the two junctions in proportion to the temperature difference
Thermometer
An instrument used to measure temperature
How to calibrate a thermometer?
- Ice-point method (put it in pure melting ice and mark point as 0)
- Boiling-point method (put it in boiling water and mark point as 100)
Divide the remaining area into equal parts
Sensitivity
A large expansion to small stimuli or change