P1 V2 Flashcards

1
Q

why do giant ionic lattices have high melting and boiling points

A

due to the high amount of energy needed to break the strong electrostatic forces

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2
Q

what happens at the melting point

A

melting and freezing

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3
Q

what happens at the boiling point

A

boiling and condensing

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4
Q

what are the properties of small molecules

A

they are usually gases or liquids which have low boiling and melting points because the intermolecular forces need to be overcome not the covalent bonds
the strength of the intermolecular forces increase with the size but because they are small they have low melting and boiling points
They do not conduct electricity due to not having an overall electric charge

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5
Q

what are the properties of polymers

A

polymers are long molecules, this means it has a stronger intermolecular force meaning a higher boiling and melting point. this means that they are normally solids at room temp, polymers have a lower boiling and melting point that giant covalent and ionic structures

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6
Q

what are the properties of giant covalent structures?

A

they have very high melting and boiling points. this is because each atom is connected by a stong covalent bond which is needed to be overcome in order to melt ot boil the element. One example of this is diamond where each carbon atom has a strong covalent bond with 4 other carbon atoms.

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7
Q

what are the properties of metals and alloys and what are done to pure metals that are too soft by themselves?

A

metals are normally have giant structures with strong metallic bonding meaning they have high melting and boiling points, this is due to the strong electrostatic force between the negative delocalised electron and the positive metal ions. In pure metals, atoms are in layers allowing it to be malleable, this means that they are normally too soft for their uses so they are mixed with other metals to make a metal alloy this distorts the layers and makes its harder to slide over each other, meaning it is less malleable

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8
Q

why are metals good conductors of heat and electricity

A

because each metal atom has a delocalised electron, this leads to the structure having a sea of delocalised electrons which can carry charge. When it comes to heat, energy can be carried through the sea of delocalised electrons meaning it is a good thermal conductor

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9
Q

what is avogadro’s constant

A

6.02 X 10^23

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10
Q

what is the limiting reactant in a chemical equation and why is it common?

A

a limiting reactant is the substance that runs out before the other, the other is in excess to ensure the limiting reactant is completely used up.

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11
Q

what is the equation for concentration and what are the units ?

A

concentration (g/dm^3) = mass (g) / volume (dm^3)

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12
Q

what is OILRIG

A

oxidation is loss ( of electrons)

reduction is gain (of electrons)

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13
Q

what are ions?

A

ions are what is formed when an atoms loses or gains electrons to gain a full ouet shell

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14
Q

what type of substance (metal, non metal) are negative and positive ions?

A

Metals lose an outer shell electron to form a positive ion

Non-metals gain an outer shell electron to form a negative ion.

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15
Q

what are the charges of ions?

A

if you gain an electron is -1

if you lose an electron its +1

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16
Q

what is the name for structure of an ionic compound and how does this affect the electrostatic forces? How does this affect melting and boiling points?

A

Giant ionic lattices have negative and positive electrons packed together so the strong electrostatic forces between the negative and positive ions are all around. This means that it has a high melting and boiling points because it takes lots of energy to overcome these bonds

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17
Q

why can molten or dissolved ionic compounds carry charge?

A

because the ions are free to move and can carry charge. The ones that can dissolve in a solution, the ions seperate and are free to move meaning they can carry electrical charge

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18
Q

what is a covalent bond?

A

a bond between two nonmetal atoms which is joined together by strong electrostatic forces, which makes them very strong. They share the amount of atoms needed to fill up the outer shell of both atoms.

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19
Q

why are the melting points of simple molecular structures low even though they have covalent bonds?

A

The structures have feeble intermolecular forces of attraction between the molecules, only these need to be overcome and not the covalent bonds meaning that the melting and boiling points are low .

20
Q

what happens to simple molecular structures as the molecules get larger? Why don’t they carry charge?

A

Simple molecular structures get a stronger intermolecular force in between the atoms when they get bigger, this means more energy is needed to overcome the intermolecular force meaning the melting and boiling points are higher.

21
Q

what happens when a metal reacts with oxygen?

what is the reaction called when a metal gains and loses oxygen?

A

it becomes a metal oxide

when a metal gains oxygen it called oxidation and when it loses oxygen it is called a reduction reaction

22
Q

how can you reduce metal oxides? (two ways)

A

one way of reducing metal oxides is reacting them with carbon, this allow carbon to take the oxygen and make CO2, but this can only be done with elements below carbon in the reactivity series. If the element is more reactive than carbon, it can be reduced using electrolysis.

23
Q

why does metal react more with water and acid as you move up the reactivity series?

A

As you move up the reactivity series, the metals are more reactive meaning they can lose their outer shell electron easier, this means when you move up it will be more reactive with water and acid because it will lose its outer shell electron.

24
Q

what does acid + metal =?

A

salt + hydrogen

25
Q

what does metal + water =?

A

metal hydroxide + hydrogen

26
Q

what is the reactivity series in order?

A
Potassium
Sodium 
Lithium
Calcium
Magnesium
Carbon 
Zinc 
Iron
Hydrogen
Copper
27
Q

what happens to acids in a solution, how does this reaction differ when it comes to weak and strong acids?

A

Strong acids will fully ionise into H+ ions in a solution

Weak acids will only partially ionise into a solution

28
Q

why do strong acids ionise faster?

A

This is because the more H+ ions present, the faster the reaction will be, strong acids have more H+ ions meaning that the rate of reaction will be faster

29
Q

what is the pH scale measured in and how does this change?

A

each 1 change on the pH scale is 10x the amount of hydrogen ions, e.g a pH of 5 will have 100x less the hydrogen ions than a pH of 7

30
Q

what does a concentrated acid mean?

A

the more of an acid in a certain volume of water. The more acid there is, the more concentrated it is.

31
Q

what does a dilute acid mean?

A

an acid in a solution that is not very concentrated

32
Q

explain the pH scale.

A

7 is neutral (water)
anything below 7 is an acid
anything above 7 is a base
anything that dissolves in water with a base to form a substance with a higher pH than 7 is an alkali

33
Q

what is neutralisation?

A

When a base and an acid reacts with each other and forms a neutral solution. This is because of the H+ and the OH- ions

34
Q

what do metal oxides and hydroxides react with acids to form?

A

salt + water

35
Q

what are the metal oxides and hydroxides that dissolve in water called?

A

alkalis

36
Q

what does an acid + metal carbonate make?

A

water + salt + Carbon Dioxide

37
Q

What happens (in terms of ions) during electrolysis?

A

The negative ions will move towards the anode to lose electrons (oxidation)
The positive ions will move towards the the cathode and gain electrons (reduction)
this creates a flow of charge through the electrolyte

38
Q

why is electrolysis used to extract some metals?

A

this is used to get the metals more reactive than carbon a full outer shell

39
Q

why is cryolite added to aluminium oxide before electrolysis?

A

To reduce the melting point, which reduces the cost because less energy is needed to melt it.

40
Q

what is the anode and cathode made from and why?

A

Graphite (made from carbon) because it is a great conductor of electricity and can withstand very high melting and boiling points

41
Q

what are some of the defects of using electrolysis?

A

A lot of energy is needed to melt the compounds which is expensive as well as lots of energy being needed to produce the electric current.
Furthermore, the anode and cathode need to regularly be replaced.

42
Q

what is the rule when it comes to hydrogen being produced during electrolysis?

A

Hydrogen is produced at the cathode if the metal is more reactive than hydrogen.
But if it is less reactive than hydrogen (copper,silver) than that is produced at the cathode instead.

43
Q

what happens if an aqueous solution contains a halide ion (an ion in group 7, the halogens)?

A

Then the halogen will be produced at the anode, e.g chlorine gas

44
Q

structure of diamond that allows. it to have a high melting and boiling point

A

each carbon atom is covalently bonded to 4 other carbon atom, leaving no free electrons. To overcome these bonds it requires a great deal of energy which makes the melting and boiling points high

45
Q

Silicon dioxide structure

A

silicon atoms covalently bonded to oxygen atoms to form a giant covalent structure, this means they have very high melting and boiling points

46
Q

electrolysis

A

beaker with 50cm cubed of copper II chloride solution
you place a petri dish on top of the beaker and you place your two carbon anode and cathode and attach it to a power pack. Carbon should form at the cathode because it is less reactive than hydrogen and chlorine gas is produced at the anode because it is a halide ion