P1. Topic 5 Energy Changes 🥈 Flashcards

1
Q

Outline some basics of energy

A

Can’t be created nor destroyed and can only be transferred

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2
Q

What is Chemical energy

A

Energy stored in the bonds between atoms.

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3
Q

SI unit for energy

A

Joules

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4
Q

What are the Energy changes during a chemical reaction

A

Energy is released or absorbed during a chemical reaction depending on the relative energies of the bonds within the reactants and products.

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5
Q

Describe an Exothermic reaction and reaction profile

A

If the total chemical energy of the products is lower than the total energy of the reactants, energy will be released from the system into the surroundings.

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6
Q

Give an Example of an exothermic reaction

A

Combustion of methane and respiration.

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7
Q

Describe an Endothermic reaction and reaction profile

A

If the total chemical energy of the products is higher than the total energy of the reactants, energy will be absorbed from the surroundings.

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8
Q

Give an Example of endothermic reaction

A

Decomposition of water by electrolysis and photosynthesis

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9
Q

What happens to heat in an exothermic reaction

A

It is given out

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10
Q

What happens to heat in an endothermic reaction

A

It is taken in

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11
Q

List the equipment you need to measure energy transfer in a practical and state the purpose of them

A

Polystyrene cup- insulates, doesn’t allow heat to enter or escape
Thermometer- measure temperature (then calculate temperature change)
Lid- prevents heat entering or escaping
Beaker- provides stability for the polystyrene cup
Measuring cylinder- allow the same volume of acid to be used each time

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12
Q

State the variables in the energy transfer practical

A

Independent- concentration of acid
Dependant- temperature change
Control- volume of acid and initial temperature as well as mass of metal

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13
Q

What does temperature increase indicate

A

The reaction is exothermic

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14
Q

What does temperature decrease indicate

A

The reaction is endothermic

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15
Q

Describe the energy changes (exothermic/endothermic) practical (6)

A

Place the polystyrene cup inside the glass beaker to make it more stable.
Measure an appropriate volume of the solution, eg 25 cm3.
Measure an appropriate mass of the solid, or select a suitable sized piece of metal.
Place the solution in a polystyrene cup.
Record the initial temperature of the solution.
Add the solid and record the highest or lowest temperature obtained.
Calculate the temperature change by doing final final temperature - initial temperature

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16
Q

What do reaction profiles show?

A

Energy changes

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17
Q

Is this reaction profile endothermic or exothermic and why
^
| ^
| / \
|____/ \
| \___
|_______________>

A

Exothermic, products are below reactants

18
Q

Is this reaction profile endothermic or exothermic and why
^
| ^
| / \____
|____/
|
|_______________>

A

Endothermic, products are higher than reactants

19
Q

What is labelled x
^
| ^
| / \
x|___/ \
| \___
|_______________>

20
Q

What is labelled x

^
| ^
| / \
|___/ \
| \___
|_______________>
x

A

Progress of reaction

21
Q

What is labelled x
^
| ^
| / \
|_ x_/ \
| \___
|_______________>

22
Q

What is labelled x
^
| ^
| / \
|___/ \
| \ x
|_______________>

23
Q

What is labelled x
^
| ^
| / | \
|___/ |x \
| \___
|_______________>

A

Activation energy

24
Q

What is labelled x
^
| ^
| / \
|___/ \
| |x \___
|_______________>

A

Overall energy change

25
How should your arrows look when labelling activation energy and overall energy change
The arrows should always touch the peak and align
26
What is happening to bonds during an endothermic reaction
Bonds are breaking, eg. HCl —energy supplied—> H + Cl ^ ^ | | Strong bond Broken bond
27
What is happening to bonds during an exothermic reaction
Bonds are forming, eg. C + O —energy supplied—> CO + energy released ^ | Strong bond formed
28
How to calculate Overall energy change
Overall energy change = energy required to break bonds - energy released by forming bonds
29
How to calculate energy required to break bonds
The known bond energies will be given on the exam paper, Find the sum of the bond energy of the reactants, big numbers are included and should be X(bond energy)
30
How to calculate energy released by forming bonds
The known bond energies will be given on the exam paper, Find the sum of the bond energy of the products, big numbers are included and should be X(bond energy)
31
What does negative overall energy change indicate
Exothermic reaction
32
What does positive overall energy change indicate
Endothermic reaction
33
What do chemical reactions in a cell produce
Electricity
34
What is an electrochemical cell made of
Two different electrodes that are in contact with an electrolyte
35
What is the electrode usually made of
Aqueous or molten solution containing ions that move towards the electrodes
36
What does the voltage of a cell depend on
Type of metal Difference in reactivity Electrolyte used Batteries connected result in bigger voltage
37
38
What happens to reactants in non rechargeable batteries
They get used up
39
What type of battery is an alkaline battery and is the reaction reversible?
Non-rechargeable and the reaction is irreversible
40
How can the reaction in a rechargeable cell be reversed l
By connecting it to an external electric current
41