P Block Flashcards

Basic knowledge

1
Q

Electronic configuration

A

(ns1)(np1)

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2
Q

Oxidation state

A

+3

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3
Q

Anomalous behavior

A

Boron(nonmetal)

All others are metal

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4
Q

Radii trend

A

Doesn’t increase on descending the group

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5
Q

Unusual element

A

Gallium shows half expected radius

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6
Q

Gallium indium and tellurium

A

Outer shell d10 electronic configuration

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7
Q

GA in tl

A

Show poor shielding effect

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8
Q

4f electron

A

TI IS LARGER THAN IN

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9
Q

Ionic radii m3+ exists

A

Atomic radii b3+ doesn’t exist

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10
Q

Down the group+1 oxidation state increase and more stable than +3

A

Due to inert pair effect

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11
Q

Melting point

A

Regular trend

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12
Q

Structure of boron

A

20 faced icosahedral

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13
Q

Variation of boiling point

A

Expected

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14
Q

Density

A

Increase down the group

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15
Q

IE

A

Doesn’t follow regular trend

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16
Q

Standard electrode potential

A

E°=(M+|M)

17
Q

Reaction with oxygen

A

All element on burning form M2O3

Ti2O3

18
Q

For aluminium∆Hf=???

A

-1670kj

19
Q

Reactions with water

A

Forms protective layer of M2O3

20
Q

Oxides

A

M2O3

21
Q

Halide

A

MCl3

22
Q

Boron and silicone

A

Forms alloys spontaneous and inflammable

23
Q

Reaction with alkalis

A

BO4. SiO4

24
Q

14th group electronic configuration

A

new np2

25
Q

Oxidation state

A

+4

26
Q

Metallic character

A

Starts from non Metal ends on metal

27
Q

Melting point

A

Decreases down the group

28
Q

Boiling point

A

Decreases down the group

29
Q

Properties of An And Pb

A

Most electronegative

30
Q

Catenation

A

Ability of atoms to link one another

Through covalent bonds

31
Q

Catenation

A

Decreases down the group

32
Q

Bonding

A

Besides pπ-pπ bonds

Carbon forms bond with itself

33
Q

Dπ-pπ

A

Compounds with Si

However can form double bonds
Through Dπ-pπ bonding in Which p orbital is expanded

34
Q

Expansion of p orbital is called

A

Back bonding

35
Q

Maximum covalence

A

Carbon