P Block Flashcards

1
Q

Calomel

A

Hg2Cl2
Used as secondary reference electrode

When in contact with ammonium hydroxide turns black
Hg2Cl2 +NH4OH—-> HgNH2Cl +Hg +NH4Cl+ H2O

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2
Q

Apatite family

A
Ca9(PO4)6.CaX2. (X=F, Cl, Br)
Flourapitite Ca9(PO4)6.CaF2
Found in phosphate rocks
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3
Q

Metalloids in N family

A

As(Arsenic) Sb(Antimony)

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4
Q

Reducing character of hydrides of N family

A

NH3

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5
Q

Why are group 17 molecules coloured?

A
Cuz HOMO LUMO gap kam hai
F2   yellow gas
Cl2  greenish yellow gas
Br2  red liquid
I2    violet solid
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6
Q

Haber’s process

A

N2 +3H2——-> 2NH3
200atm,700K, iron oxide with K2O&Al2O3
Mo as promoter

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7
Q

Physical state of N family

A

N gas ,P soft solid, rest all solid

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8
Q

State of N2O3

A

Blue solid

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9
Q

State of NO2

A

Brown gas

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10
Q

Trends in melting point of N family

A

N<p>Sb>Bi

N</p><p></p>

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11
Q

Trends in electron affinity of O family

A

S>Se>Te>O

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12
Q

Trends in electron affinity of F family

A

Cl>F>Br>I

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13
Q

Trends in electron affinity of He family

A

Ne>Ar>Kr>Xe>Rn>He

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