OZ4: Rates of Reaction Flashcards
What is meant by the “rate of reaction”?
How quickly reactants are converted into products
Give the formula for calculating the rate of reaction.
Change in property/time taken
Give 5 ways change in property can be measured to determine rate of reaction.
- Chemical analysis
- Volume of gases
- Mass changes
- PH measurement
- Calorimetery
Why is it important for scientists to measure rates of reactions?
- A reaction occurring too quickly can be dangerous
- A reaction occurring too slowly is impractical because it ties up equipment and people, which costs money
Give an example in which the volume of a gas is measured to determine rate of reaction.
- Reaction between calcium carbonate and HCl produces CO2
- Gas is collected in a measuring cylinder
Give an example in which mass change is measured to determine rate of reaction.
- Reaction between calcium carbonate and HCl produces CO2
- Mass lost of calcium carbonate can be recorded against time
Give an example in PH is measured to determine rate of reaction.
- Reaction between calcium carbonate and HCl produces CO2
- HCl concentration falls so the PH of the reaction mixture also falls
What does a calorimeter do?
Measures change in a reaction’s colour
Give an example where calorimetery is used to determine rate of reaction.
- When zinc reacts with copper (II) sulphate, the blue coloration of copper sulphate decreases
- Measure the rate of this colour decreasing against time
Explain how chemical analysis can determine the rate of reaction.
- Involves taking samples of the reaction mixture at regular intervals
- Stopping reaction in a sample (quenching) before analysis
Give an example in which chemical analysis is used to determine rate of reaction.
- Iodine and propanone react in the presence of an acid catalyst
- The sample is extracted and quenched by adding sodium hydrogen carbonate, neutralising the acid
- Amount of iodine remaining is determined by titration
How do you plot a graph for the rate of reaction?
- Time is plotted on the x axis
- Change in property is plotted on the y axis
Give the conditions for a successful collision.
- Must collide in the right direction
- Must collide with correct orientation
- Must collide with the minimum amount of Kinetic energy required
What are liquid and gas particles always doing?
Always moving and colliding
Why is initial reaction the fastest?
- As the reaction continue, the concentration of reactants decreases
- Less frequent collisions between reactant particles
- Decreased rate of reaction