Oxidising power of halogens Flashcards
oxidation number of an element
always 0
oxidation number of ions
same as its charge (NaCl has no charge, so Na is +1 and Cl is -1)
trend in oxidation numbers
the more positive the number, the more it has been oxidised (the more negative electrons it has lost). The more negative, the more reduced
rule exceptions
H is usually +1, but in metal hydrides its -1
O, -2 (peroxides -1, and the compound OF2, where its +2)
F, -1
Cl, -1 (except for with F or O where its positive)
Which halogen has the strongest oxidising power (i.e which is best at stealing electrons?)
Chlorine, bromine then ikodine
Explanation of trend in oxidising power
Down the group it becomes harder to gain an electron because atoms are larger and there is more shielding (due to extra electron shell).
Colour of;
Bromide
Iodide
Yellow
Brown
Which halogen has the strongest reducing power?
Iodine
Bromine
Chlorine
Explanation of reducing power
When a halide acts as a reducing agent it is losing electrons. Down the group it becomes easier to lose an electron because ions are larger and there is more shielding due to an extra electron shell.