Oxidations Flashcards
1
Q
Primary alcohol –> aldehyde
A
Swern (oxalyl chloride, DMSO, Et3N)
OR
DMP
2
Q
Primary alcohol –> acid
A
Jones (CO3, H2SO4)
3
Q
Secondary alcohol –> ketone
A
Swern (oxalyl chloride, DMSO, Et3N)
OR
DMP
4
Q
Aldehyde –> acid
A
Pinnick (NaClO2, NaH2PO4, 2-methyl-2-butene)
5
Q
Ketone –> ester
A
Baeyer-Villiger (mCPBA)
6
Q
Alkene to aldehyde/ketone
A
(i) O3
(ii) Me2S
7
Q
Alkene to anti-Markovnikov alcohol
A
(i) BH3
(ii) H2O2
8
Q
Alkene to Markovnikov alcohol
A
(i) Hg(OAc)2
(ii) NaBH4
9
Q
Alkene to epoxide
A
mCPBA
10
Q
Alkene to diol
A
OsO4