Oxidation numbers Flashcards

1
Q

What are the oxidation number rules?

A

A set of rules to work is a redox is taking place and if so, which element is reduced and oxidised

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2
Q

What is the most important oxidation rule?

A

Oxidation refers to an individual atom and are mostly always the same element and they are written with the +/- sign before the number

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3
Q

What is oxidation number significance in covalent compounds?

A

It has no significance in covalent compounds (any compound with covalent bonding)

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4
Q

What is the first oxidation number rule?

A

Atoms of uncombined always have an oxidation number of 0

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5
Q

What is the second oxidation number rule?

A

Group 1 element atoms have an oxidation number of +1

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6
Q

What is the third oxidation number rule?

A

Group 2 element atoms have an oxidation number of +2

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7
Q

What is the fourth oxidation number rule?

A

Fluorine atoms have an oxidation number of -1

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8
Q

What is the fifth oxidation number rule?

A

Oxygen atoms have an oxidation number of -2 except when in a peroxide (e.g, H2O2 - hydrogen peroxide) then it is -1

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9
Q

What is the sixth oxidation number rule?

A

Hydrogen atoms have an oxidation number of +1 except when in a metal hydride (which is only metal & hydrogen , e.g, LiH) then it is -1

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10
Q

What is the oxidation number rule about simple ions?

A

The sum of the oxidation numbers equals the charge on the ion, e.g, I- = -1

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11
Q

What is the oxidation number rule about compound ions?

A

The oxidation numbers must all add up to the charge of the ion (in polyatomic ions), e.g, SO4 2- = -2

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12
Q

What is the oxidation number rule about neutral compounds?

A

The sum of oxidation numbers is 0 (but must account for formula in compounds)

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13
Q

What do roman numerals indicate?

A

The oxidation number of the element and they are always positive

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14
Q

What do roman numerals after a metal indicate?

A

The oxidation number of the metal (but are only used when the metal can form more than one ion e.g, Fe(III) = Fe 3+

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15
Q

What do roman numerals written after a compound ion indicate?

A

The oxidation number of the element in the ion which is not oxygen

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16
Q

What is oxidation (in terms of oxidation number)?

A

Increase in oxidation number

17
Q

What is reduction (in terms of oxidation number)?

A

Decrease in oxidation number

18
Q

How do you work out which element has been oxidised and reduced using oxidation numbers?

A

First, assign oxidation numbers to everything in the equation (no balancing) and then identify the increase (oxidation) and decrease (reduction)

19
Q

How do you describe that an element has been oxidised?

A

(The element) has been oxidised because it’s oxidation number has increased from (X) to (Y)

20
Q

How do you describe if an element has been reduced?

A

(The element) has been reduced because it’s oxidation number has decreased from (X) to (Y)