Outcome 1 Flashcards

1
Q

what is an atomic emission spectrum?

A

by passing the light of an element through a prism it produces an atomic emission spectrum for that element

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2
Q

who is given credit for the periodic table we see today?

A

dmitri mendeleev

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3
Q

how many elements in the periodic table?

A

118 known elements

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4
Q

what do elements in the same group and period have in common?

A

group- similair chemical properties i.e. same number valence of electrons
period- have same number of atomic orbitals

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5
Q

what is the oxidising strength of electrons?

A

how readily an atom gains electrons

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6
Q

what is the reducing strength of electrons?

A

how readily an atom loses electrons

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7
Q

how can the trends of atomic size be determined?

A

going across a period it decreases

going down a group it increases

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8
Q

how can the trends of metallic character be determined?

A

going across a period it decreases

going down a group it increases

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9
Q

how can the trends of reactivity be determined?

A

going across a period it decreases

going down a group it increases

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10
Q

how can the trends of electronegativity be determined?

A

going a period across it increases

going down a group it decreases

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11
Q

how can the trends of oxidising strength be determined?

A

going across a period it increases

going down a group it decreases

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12
Q

how can the trends of reducing strength be determined?

A

going across a period it decreases

going down a period it increases

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13
Q

what is ionisation energy?

A

the energy required to remove an electron from a gaseous atom

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14
Q

how can the trends of ionisation energy be determined?

A

going across a period it increases

going down a group it decreases

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15
Q

what is an ionic bond?

A

when two atoms gain or lose electrons to form an ionic lattice held together via electrostatic attraction

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16
Q

what is the structure of an ionic lattice?

A
  • held together via electrostatic attraction
  • each cation is surrounded by anions and vise-versa
  • the relative size and numbers of ions present determine the ‘actual’ lattice structure
17
Q

properties of ionic compounds with relation to structure

A
  • usually crystalline solids, due to the 3D patterns of the lattice
  • have high melting + boiling points, due to the large amount of energy needed to separate ions
  • do not conduct electricity in the solid form, due to the fixed particles
  • are hard, due to the strong ionic bonds in the lattice
  • often dissolve in water, as water molecules are able to move between ions and free them by disrupting the crystal structure
  • are brittle, repulsion between like charges shatters the crystal
  • in the molten form ions are able to slide past on another and can therefore conduct electricity
18
Q

uses of ionic compounds

A

sodium hydrogen carbonate- an enviro friendly cleaning agent
ammonium nitrate- used to manufacture explosives and fertilisers
nitrate, nitrite + sulfite- used to preserve food

19
Q

why is copper so widely used?

A

low melting point and the ease in which it could be extracted from its ore

20
Q

why has aluminium only recently become popular?

A

was difficult to extract from its ore despite being extremely abundant

21
Q

properties of metals

A
  • lustrous (due to the mobile electrons being able to reflect light)
  • ductile + malleable (layers of atoms can move past one another without disrupting the force between the cations and delocalized electrons)
  • good conductor of heat (the bumping of the electrons transfers heat) + electricity (the movement of the delocalized e- form an electric current)
  • often hard
  • generally have high density (metallic ions are closely packed within the lattice)
22
Q

substitutional alloy vs interstitial alloy

A

s- if the atoms of the metals are about the same size they can replace each other in the metal crystals
i- if they sizes differ greatly the smaller atoms may fit into the spaces between the larger atoms

23
Q

give 2 examples of alloys and their composition

A

stainless steel- 73% Fe, 18% Cr, 9% Ni

sterling silver- 92.5% Ag, 7.5% Cu

24
Q

what is work hardening?

A

bending or hammering cold metals causes their crystal grains to become smaller therefore bending becomes more difficult

25
Q

difference between annealing, quenching and tempering a metal?

A

a- heated until red hot, cooled slowly, larger crystals are formed so the metal becomes softer, used to restore ductility
q- heated until red hot, cooled in water, smaller crystals formed, harder and more brittle metal formed
t- quenched metals reheated, cooled slowly, reduces brittleness, remains hard

26
Q

what doesn’t the lattice model tell us about properties?

A

magnetism + strength

27
Q

metal strength is explained by what model?

A

ball bearing model

  • when a metal bends, layers of atoms slide over each over
  • easier they slide=easier the metal bends
  • metals w/ larger grains have fewer dislocations=bend easier
  • metals w/ small grains have more dislocations=do not bend as easily
  • grains are the areas of close packed metals