Organic (unit 4) Flashcards

1
Q

multiple bonds are _____ reactive than single bonds

A

more, as they are much more unstable

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2
Q

atoms that are more ________ electronegative will replace another species that isnt as ________

A

electronegative

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3
Q

what are addition reactions?

A

2 molecules combining, something is added to a molecule

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4
Q

where do addition reactions occur?

A

only at double or triple bonds

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5
Q

what are the three subclasses of addition reactions?

A

halogenation: adding halogens
hydrogenation: adding hydrogens
hydrohalogenation: adding acids

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6
Q

what are substitution reactions?

A

one species being replaced with another more electronegative atom

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7
Q

substitution reactions always happen to _______ organics

A

saturated

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8
Q

how many species will substitute during a substitution reaction

A

only one

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9
Q

_____ is usually required in a substitution reaction in the form of ____ or ____

A

energy, uv light, heat

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10
Q

addition always happens with ______ compounds

A

unsaturated

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11
Q

what is an elimination reaction?

A

atoms leaving a molecule

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12
Q

elimination reactions usually produce ______ or ______ bonds

A

double, triple

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13
Q

what is steam cracking?

A

high temp steam hits ethane and removes hydrogens, forms ethene

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14
Q

what is dehydrating?

A

removing HOH, an acid catalyst usually is involved

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15
Q

what is dehydrohalogenation?

A

addition of a base to a halogenated hydrocarbon producing a double bond

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16
Q

what are esters?

A

natural/artificial fragrance and flavourings, perfumes, fats, etc

17
Q

esters are the “child” of two parent molecules, what are they?

A

carboxylic acid and alchohol

18
Q

what is the joining of esters called?

A

esterification

19
Q

monomers join to become ______?

A

polymers

20
Q

what is the process of making polymers?

A

polymerization

21
Q

what are the two types of polymerization?

A

addition polymerization, and condensation polymerization

22
Q

what is addition polymerization?

A

double bonded monomers breaking to join up, creates a chain reaction

23
Q

what is condensed polymerization?

A

always two different polymers (called co-polymer)

24
Q

what is another name for condensed polymerization?

A

dehydration

25
Q
A
26
Q

higher molecular _____ has higher _______ = higher ________

A

weight, london dispersion force, bp/mp

27
Q

more polar = more _____ = higher ______

A

sticky, bp/mp

28
Q

hydrogen bonds are _______

A

super polar

29
Q

read: solubility “like likes like”

A
  1. nonpolar dissolves nonpolar
  2. polar dissolves polar
  3. hydrogen bonding dissolves hydrogen bonding
30
Q

what does a longer chain mean for solubility?

A

less solubility

31
Q

what is a homologous series?

A

a family of hydrocarbons with similar chemical properties who share the same general formula

32
Q

polar vs non polar

A

a polar molecule will usually be asymmetrical and a non-polar molecule will usually be symmetrical