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Chemistry Unit 4 > Organic Synthesis > Flashcards

Organic Synthesis Flashcards

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1
Q

Acyl chloride/anhydride to N-substituted amide

A
  • nucleophilic addition elimination
  • R’NH2
  • reflux
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2
Q

acyl chloride/anhydride to ester

A
  • nucleophilic addition elimination
  • R’OH
  • reflux
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3
Q

Acyl chloride/anhydride to amide

A
  • nucleophilic addition elimination
  • NH3
  • reflux
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4
Q

Acyl chloride/anhydride to carboxylic acid

A
  • H2O
  • nucleophilic addition elimination
  • reflux
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5
Q

Carboxylic acid to ester

A
  • R’OH
  • conc H2SO4
  • esterification(condensation)
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6
Q

Carboxylic acid to aldehyde

A
  • LiAlH4

- reduction

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7
Q

Aldehyde to carboxylic acid

A
  • K2Cr2O7/H+
  • oxidation
  • reflux
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8
Q

Alcohol to carboxylic acid

A
  • K2Cr2O7/H+
  • oxidation
  • reflux
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9
Q

Aldehyde to alcohol

A
  • reduction

- NaBH4

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10
Q

Alcohol to aldehyde

A
  • K2Cr2O7/H+
  • oxidation
  • distill
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11
Q

Alcohol to ester

A
  • R’COOH
  • esterification(condensation)
  • conc H2SO4
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12
Q

Alcohol to ketone

A
  • K2Cr2O7/H+
  • oxidation
  • reflux
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13
Q

Ketone to alcohol

A
  • NaBH4

- reduction

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14
Q

Alcohol to alkene

A
  • conc H2SO4
  • elimination
  • reflux
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15
Q

Alkene to alcohol

A
  • H2O

- electrophilic addition

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16
Q

Alkene to haloalkane

A
  • HBr
  • electrophilic addition
  • room temp
17
Q

Haloalkane to alkene

A
  • hot conc and alcoholic KOH

- elimination

18
Q

Alcohol to haloalkane

A
  • NaBr
  • nucleophilic substitution
  • conc H2SO4
  • reflux
19
Q

Haloalkane to alcohol

A
  • NaOH
  • nucleophilic substitution
  • reflux
20
Q

Haloalkane to amine

A
  • excess NH3

- nucleophilic substitution

21
Q

Haloalkane to nitrile

A
  • KCN
  • nucleophilic substitution
  • aqueous ethanol solution
  • reflux
22
Q

Nitrile to amine

A
  • H2/Ni

- reduction

Chemistry Unit 4 (3 decks)

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