Organic reagents and their reactions Flashcards

1
Q

Homolytic fission defintion

A

The braking of a covalent bond, with one of the bonded electrons going to each atom,forming two radical.

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2
Q

A radical is what?

A

A radical is a species with an unpaired electron.

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3
Q

Heterolytic fission defintion

A

The breaking of a covalent bond with both of the bonded electrons going to one of the atoms, forming a cation and an anion.

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4
Q

What is homolytic fission?

A

Each bonded atom takes one of the shared pair of electrons, each atom has an unpaired electron and is called a radical.
1) Two species of the same type are produced.
X-Y ——> X + Y two radicals

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5
Q

What is heterolytic fission?

A

One of the bonded atom takes both of the shared pair of electrons. Two ions are produced: 1) Anion which took two electrons. 2)Cation which got took no electrons when the bond broke.

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6
Q

Define nucleophile

A

A nucleophile is an atom(or group of atoms) that is attracted to an electron-deficient centre or atom,where it donates a pair of electrons to form a new covalent bond.

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7
Q

Define electrophile

A

An atom( or group) that is attracted to an electron rich centre or atom, where it accepts a pair of electrons to form a new covalent bond.

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8
Q

Define addition reaction

A

A reaction in which a reactant is added to an unsaturated molecule to make a saturated molecule.

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9
Q

define substitution reaction

A

A reaction in which an atom or group of atoms is replaced with a different atom or group of atoms.

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10
Q

Define elimination reaction

A

An elimination reaction refers to the removal of a molecule from a saturated molecule to make an unsaturated molecule.

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