Organic Reactions Flashcards

1
Q

Alkene -> Alkane

A

H2/Ni, 150*C

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2
Q

Alkene -> Haloalkane

A

Hydrogen halide

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3
Q

Alkene -> Alcohol

A

H2O (steam)/H3PO4 300*C

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4
Q

Alkane -> Haloalkane

A

Halogen, UV

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5
Q

Haloalkane -> Nitrile

A

NaCN or KCN in ethanol + heati

Water is a nucleophile

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6
Q

Haloalkane -> Alcohol

A

NaOH(aq)

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7
Q

Haloalkane -> Amine

A

NH3 in ethanol

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8
Q

Alcohol -> Aldehyde

A

Potassium dichromate/H2SO4, distil

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9
Q

Alcohol -> Carboxylic acid

A

Potassium dichromate/H2SO4, reflux

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10
Q

Alcohol -> Alkene

A

H2SO4 or H3PO4/ heat

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11
Q

Alcohol -> Haloalkane

A

Hydrogen halide
For Cl reaction too slow for primary, PCl3 is better
For Br, NaBr and H2SO4 where HBr reacts
For I, Na + H3PO4

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12
Q

Alcohol -> Ester

A

Carboxylic acid / conc. H2SO4

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13
Q

Alcohol -> Ester

A

Acid anhydride / conc. H2SO4

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14
Q

Alcohol -> Ester

A

Acryl chloride / conc. H2SO4

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15
Q

Aldehyde/ketone -> Hydroxynitrile

A

NaCN(aq)/H+(aq)

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16
Q

Aldehyde/ketone -> Alcohol

A

NaBH4

17
Q

Ester -> Carboxylate salt

A

Hot aqueous alkali

18
Q

Carboxylic acid -> Ester

A

Alcohol/conc. H2SO4 reflux

19
Q

Carboxylic acid -> Acryl chloride

A

PCl5 cold (steamy fumes produced)

20
Q

Acryl chloride -> Carboxylic acid

A

H2O

21
Q

Acryl chloride -> Primary amide

A

NH3

22
Q

Acryl chloride -> Secondary amide

A

Primary amine

23
Q

Acryl chloride -> Ester

A

Alcohol

24
Q

Nitrile -> Amide

A

H2/Ni high temperature

25
Q

Nitrile -> Carboxylic acid

A

H2O, HCl, heat

26
Q

Amide -> Carboxylic acid and Amine

A

HCl(aq) heat or NaOH heat

27
Q

Ester -> Carboxylic acid and Alcohol

A

HCl(aq) heat or NaOH(aq) heat

28
Q

Phenol -> Bromophenol

A

Br2

29
Q

Alkene -> dibbromoalkane

A

Br2

30
Q

Benzene -> Nitrobenzene

A

Conc. HNO3, conc. H2SO4 50*C

31
Q

Nitrobenzene -> Phenylamine

A

Tin, conc. HCL reflux

Then, NaOH (turns NH3+ into NH2)

32
Q

Benzene -> Chlorobenzene

A

Cl2, AlCl3

33
Q

Benzene -> Bromobenzene

A

Br2, FeBr3

34
Q

Benzene -> Methylbenzene

A

CH3Cl, AlCl3

35
Q

Benzene -> Phenylethanone

A

CH3COCl, AlCl3

36
Q

Alkene into polymer

A

Nickel catalyst and heat

37
Q

Carboxylic acid into Alcohol

A

LiAlH4
0*C
Dry ether

38
Q

Aldehyde into hydroxynitrile

A

HCN

39
Q

Hydroxynitrile into amine

A

LiAlH4

Dry ether