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organic reactions Flashcards

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1
Q

haloalkane to amine
mechanism
reagents
conditions

A

nuc sub
excess NH3
ethanol heat pressure

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2
Q

haloalkane to alcohol (2’ or 1’)
mechanisms
reagents
conditions

A

nuc sub
NaOH
aqueous heat reflux

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3
Q

haloalkane to nitrile

A

nuc sub
KCN
water and ethanol

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4
Q

Alkane to haloalkane
mechanism
reagent
condition

A

free radical sub
Br2 / Cl2
UV light

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5
Q

Alkane to CO2 + H2O
reaction type
reagent

A

combustion
O2

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6
Q

haloalkane to alkene
mechanism reagents conditions

A

elimination
KOH
ethanol reflux

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7
Q

alkene to haloalkane
mechanism reagent

A

electrophilic add
HBr / HCl / Br2 / Cl2

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8
Q

Alkene to alkyl hydrogen sulfate
mechanism reagent

A

electrophilic add
H2SO4

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9
Q

Alkyl hydrogen sulfate to alcohol

A

H2O

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10
Q

Alkene to alcohol

A

direct hydration
steam
H3PO4

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11
Q

Alcohol to alkene

A

elimination
hot con H2SO4
600K

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12
Q

1’ Alcohol to carboxylic acid

A

oxidation
K2Cr2O7 / H2SO4
reflux excess oxidising agent

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13
Q

1’ alcohol to aldehyde

A

oxidation
K2Cr2O7 / H2SO4
distillation

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14
Q

2’ alcohol to ketone

A

oxidation
K2Cr2O7 / H2SO4
reflux or distillation

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15
Q

ketone to 2’ alcohol

A

nuc add
reduction
NaBH4
acidic solvent

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16
Q

aldehyde to carboxylic acid

A

oxidation
K2Cr2O7
reflux

17
Q

Aldehyde to hydroxy nitrile

A

KCN
aqueous ethanolic

18
Q

ketone to hydroxy nitrile

A

KCN
aqueous ethanolic

19
Q

carboxylic acid to ester

A

conc H2SO4

20
Q

water to carboxylic acid alcohol

A

acid hydrolysis HCl

21
Q

ester to salt (COONa) alcohol

A

alkali hydrolysis NaOH

22
Q

nitrile to amine

A

Ni/H2

23
Q

amine to 2’ 3’ amine, ammonium quaternary salt

A

xxs haloalkane

24
Q

glucose to alcohol

A

yeast, 35 degrees, NO oxygen

chem (9 decks)

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