Organic reactions Flashcards

1
Q

Addition reactions all begin with…?

A

Alkenes

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2
Q

Addition reaction of;
Alkene → Alkane
requires what catalyst…?

A

Pt or Ni

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3
Q

Addition reaction of;
Alkene → alcohol
needs what?
what catalyst?

A

Water

Catalyst = dilute acid

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4
Q

Addition reaction of
Alkene → haloalkane
needs what?

A

HBr/HCl (unsymmetrical)
or
Br2 or Cl2 (symmetrical)

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5
Q

Alkenes being oxidised used what and form what?

A

Use KMnO4 and forms an alcohol with 2 OH groups

one on each of the Carbons in the double bond

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6
Q

What reaction will tell the difference between an alkene and an alkane?

A

Oxidation with KMnO4 - alkene will react and decolourise it and alkane will not so colour remains.

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7
Q

What do you get when you oxidise an alcohol with Cr2O7-2?

A

Carboxylic Acid

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8
Q

What does Substitution reaction mean?

A

Substitute one functional group for another.

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9
Q

What does a substitution reaction between an alkane and Br2 need and what does it make?

A

Needs UV light and makes a haloalkane.

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10
Q

What catalyst does a substitution reaction going from an alcohol to a haloalkane need? What is the reactant?

A

Catalyst is ZnCl2

Reactant is HCl

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11
Q

A substitution reaction between a haloalkane and OH- forms what?

A

Alcohol

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12
Q

A substitution reaction between a haloalkane and alcoholic NH3 forms what?

A

Amine

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13
Q

What does elimination reaction mean?

A

Functional groups are eliminated and double bonds are formed.

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14
Q

Haloalkanes form alkenes (elimination) when mixed with what?

A

KOH or NaOH

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15
Q

What type of reaction is

alkene + H2 (Pt or Ni) → alkane

A

addition

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16
Q

What type of reaction is

alkane + Br2 → haloalkane

A

substitution

17
Q

What type of reaction is

haloalkane + OH- → alcohol

A

substitution

18
Q

What type of reaction is

haloalkane + KOH/NaOH → alkene

A

elimination

19
Q

What type of reaction is

alcohol (conc H2SO4) → alkene

A

elimination

20
Q

An elimination reaction starting with an alcohol needs what catalyst?

A

concentrated sulfuric acid

21
Q

What type of reaction is

alkene (KMnO4) → (di) alcohol

A

oxidation

22
Q

What type of reaction is

alcohol (Cr2O7-2) → carboxylic acid

A

oxidation

23
Q

What type of reaction is

alkene + H2O (dilute acid) → alcohol

A

addition

24
Q

What type of reaction is

alcohol + HCl (ZnCl2) → haloalkane

A

substitution

25
Q

What type of reaction is

alkene + HCl/HBr → haloalkane

A

addition

26
Q

What type of reaction is

alkene + Br2/Cl2 → haloalkane

A

addition

27
Q

What type of reaction is

haloalkane + NH3(alc) → amine

A

substitution