Organic Introduction Flashcards

1
Q

What is a hydrocarbon

A

Is a compound consisting of hydrogen carbon only

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2
Q

Molecular formula definition

A

The formula which shows the actual number of each type of atom.

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3
Q

Empiracle formula

A

shows the simplest whole number ratio of atoms of each element in the compound

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4
Q

General formula

A

Algebraic formula for a homologous series e.g. CnH2n

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5
Q

Structual formulan

A

Shows the minimal detail that shows the arrangement of atoms in a
molecule, eg for butane: CH3CH2CH2CH3 or CH3(CH2)2CH3,

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6
Q

Displayed formula:

A

isplayed formula: show all the covalent bonds and atoms present in a molecule

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7
Q

Functional group

A

Is an atom or group of atoms which when present in different molecules
causes them to have similar chemical properties

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8
Q

Homologous series

A

are families of organic compounds with the same functional
group and same general formula.
•They show a gradual change in physical properties (e.g. boiling point).
• Each member differs by CH2 from the last.
• same chemical properties.

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9
Q

General rules for naming carbon chains

A
  • count the longest carbon chain and name appropriately
  • Find any branched chains and count how many carbons they contain
  • Add the appropriate prefix for each branch chain
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10
Q

What is homolytic fission

A

each atom gets one electron from the covalent bond
one headed arrow shows
movement of one electron

When a bond breaks by homolytic fission it forms two free radicals.
Free radicals do not have a charge and are represented by a

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11
Q

Heterolytic fission

A

One atom gets both electrons

two headed arrow shows movement of pair of electrons

Most organic reactions occur via heterolytic fission, producing ions

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12
Q

Structual isomers

A

Same molecular formula different structures (or structural formulae)

Structural isomerism can arise from
•Chain isomerism
•Position isomerism
•Functional group isomerism

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13
Q

Chain isomers

A

Compounds with the same molecular formula but different
structures of the carbon skeleton

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14
Q

Position isomers

A

Compounds with the same molecular formula but different structures due to
different positions of the same functional group on the same carbon skeleton

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15
Q

Functional group isomers

A

Compounds with the same molecular formula but with
atoms arranged to give different functional groups

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