Organic Introduction Flashcards
What is a hydrocarbon
Is a compound consisting of hydrogen carbon only
Molecular formula definition
The formula which shows the actual number of each type of atom.
Empiracle formula
shows the simplest whole number ratio of atoms of each element in the compound
General formula
Algebraic formula for a homologous series e.g. CnH2n
Structual formulan
Shows the minimal detail that shows the arrangement of atoms in a
molecule, eg for butane: CH3CH2CH2CH3 or CH3(CH2)2CH3,
Displayed formula:
isplayed formula: show all the covalent bonds and atoms present in a molecule
Functional group
Is an atom or group of atoms which when present in different molecules
causes them to have similar chemical properties
Homologous series
are families of organic compounds with the same functional
group and same general formula.
•They show a gradual change in physical properties (e.g. boiling point).
• Each member differs by CH2 from the last.
• same chemical properties.
General rules for naming carbon chains
- count the longest carbon chain and name appropriately
- Find any branched chains and count how many carbons they contain
- Add the appropriate prefix for each branch chain
What is homolytic fission
each atom gets one electron from the covalent bond
one headed arrow shows
movement of one electron
When a bond breaks by homolytic fission it forms two free radicals.
Free radicals do not have a charge and are represented by a
Heterolytic fission
One atom gets both electrons
two headed arrow shows movement of pair of electrons
Most organic reactions occur via heterolytic fission, producing ions
Structual isomers
Same molecular formula different structures (or structural formulae)
Structural isomerism can arise from
•Chain isomerism
•Position isomerism
•Functional group isomerism
Chain isomers
Compounds with the same molecular formula but different
structures of the carbon skeleton
Position isomers
Compounds with the same molecular formula but different structures due to
different positions of the same functional group on the same carbon skeleton
Functional group isomers
Compounds with the same molecular formula but with
atoms arranged to give different functional groups