ORGANIC - INTRO Flashcards

1
Q

Define empirical formula

A

The simplest whole number ratio of atoms of each element in a compound

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2
Q

Define molecular formula

A

True number of atoms of each element in a compound

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3
Q

Define general formula

A

All members of a homologous organic series follow the general formula

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4
Q

Define structural formula

A

Shows the structural arrangement of atoms within a molecule

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5
Q

Define displayed formula

A

Shows every atom and every bond in an organic compound

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6
Q

Define skeletal formula

A

Shows only the bonds and any non carbon atoms
Vertices are carbon atoms
Hydrogen is assumed to be bonded to them unless said otherwise

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7
Q

Describe cyclic alkanes

A

General formula: CnH2n
Carbon atoms are arranged in a closed ring shape

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8
Q

Describe halogenoalkanes

A

Have halogens attached to the hydrogencarbon chain
use prefixes : -fluoro, -chloro, -bromo, -iodo

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9
Q

Describe alcohols

A

OH group
e.g. butan- 2 -ol

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10
Q

Describe aldehydes

A

end in -al
functional group : double bond O and H

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11
Q

Describe ketones

A

functional group : c double bond O + R R
Prefix -oxo
When ketone has 5C’s or more it needs a number to show the position of the functional group

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12
Q

What is an isomer

A

Molecule with the same molecular formula but a different arrangement of atoms within the molecule

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13
Q

Structural isomerism

A

Different structural arrangement of atoms but the same molecular formula

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14
Q

Position isomers

A

Functional group of molecule in a different position of the carbon chain. (diagram on notes)

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15
Q

Functional group isomers

A

Different arrangement of the same molecular formula so that the molecule has a different functional group. (diagram on notes)

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16
Q

Chain isomerism

A

Hydrocarbon chain is arranged differently (diagram on notes)

17
Q

What is stereoisomerism

A

Where two (or more) compounds have the same structural formula. Differ in the arrangement of the bonds in space.
Two types : E-Z and optical
E-Z tells us about the positions of substituents at either side of the carbon-carbon double bond

18
Q

Describe Z-configuration

A

High priority substituents on same side of double bond

19
Q

Describe E - configuration

A

High priority substituents are on opposite side of double bond

20
Q

CIP rules for E-Z isomerism

A

The atom or group on each side of the double bond with higher Ar/Mr is given priority. Determines if isomer is E or Z