ORGANIC DEFINITIONS Flashcards

1
Q

Homologous series

A

Compounds which have
-The same general formula
-Similar chemical properties
-Show a gradation in physical properties
-And successive members differ by a CH2 unit

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2
Q

Hydrocarbon

A

Molecules which contain carbon and hydrogen only

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3
Q

Saturated hydrocarbon

A

Molecules which contain no C=C bonds

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4
Q

Structural isomers

A

Molecules which have the same molecular formula but different structural formula

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5
Q

Homolytic fission

A

Bond breaking in which one of the shared electrons goes to each atom

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6
Q

Free radical

A

A particle with an unpaired electron

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7
Q

Substitution

A

Replacing one atom or group with a different atom or group

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8
Q

Functional group

A

Reactive group within a compound ( C=C, OH, Cl etc)

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9
Q

Unsaturated

A

Molecules which contain at least one C=C bond or C triple bond C

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10
Q

Stereoisomers

A

Same structural formula but different arrangement of atoms in space

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11
Q

Geometric isomers

A

Same structural formula but different arrangement of atoms in space due to presence of at least one C=C

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12
Q

Sigma bond

A

A covalent bond formed by the linear overlap of atomic orbitals

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13
Q

Pi bond

A

Covalent bond formed by sideways overlap of p orbitals

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14
Q

Bond length

A

The distnace between the nuclei of two covalenty bonded atoms

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15
Q

Hydrogenation

A

Addition of hydrogen molecule across C=C

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16
Q

Monomers

A

Many small molecules which join together to form a polymer

17
Q

Polymer

A

A large moleculeformed when monomers join together

18
Q

Polymerisation

A

Joining togther of many small molecules to form a large molecule

19
Q

Primary carbocation

A

Acarbocation which has one carbon atom directly bonded to a positively charged carbon

20
Q

Electrophile

A

An ion or molecule that attacks regions of high electron density

21
Q

Primary halogenoalkane

A

A halogenoalkane that has one carbon bonded directly to the carbon that is bonded to the halogen

22
Q

Heterolytic fission

A

Bond breaking in which both electrons in the shared pair go to a single atom

23
Q

Nucleophile

A

An ion or molecule, with a lone pair of electrons, that attacks regions of low electron density

24
Q

Elimination

A

A reaction in which a small molecule is removed from a larger molecule

25
Q

Reflux

A

Repeated boiling and condensing of a reaction mixture

26
Q

Hydrolysis

A

Breaking up molcules by the reaction with water

27
Q

Primary alcohols

A

An alcohol which has one carbon bonded directly to the carbon that is bonded to the -OH group