ORGANIC DEFINITIONS Flashcards

1
Q

Homologous series

A

Compounds which have
-The same general formula
-Similar chemical properties
-Show a gradation in physical properties
-And successive members differ by a CH2 unit

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2
Q

Hydrocarbon

A

Molecules which contain carbon and hydrogen only

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3
Q

Saturated hydrocarbon

A

Molecules which contain no C=C bonds

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4
Q

Structural isomers

A

Molecules which have the same molecular formula but different structural formula

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5
Q

Homolytic fission

A

Bond breaking in which one of the shared electrons goes to each atom

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6
Q

Free radical

A

A particle with an unpaired electron

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7
Q

Substitution

A

Replacing one atom or group with a different atom or group

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8
Q

Functional group

A

Reactive group within a compound ( C=C, OH, Cl etc)

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9
Q

Unsaturated

A

Molecules which contain at least one C=C bond or C triple bond C

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10
Q

Stereoisomers

A

Same structural formula but different arrangement of atoms in space

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11
Q

Geometric isomers

A

Same structural formula but different arrangement of atoms in space due to presence of at least one C=C

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12
Q

Sigma bond

A

A covalent bond formed by the linear overlap of atomic orbitals

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13
Q

Pi bond

A

Covalent bond formed by sideways overlap of p orbitals

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14
Q

Bond length

A

The distnace between the nuclei of two covalenty bonded atoms

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15
Q

Hydrogenation

A

Addition of hydrogen molecule across C=C

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16
Q

Monomers

A

Many small molecules which join together to form a polymer

17
Q

Polymer

A

A large moleculeformed when monomers join together

18
Q

Polymerisation

A

Joining togther of many small molecules to form a large molecule

19
Q

Primary carbocation

A

Acarbocation which has one carbon atom directly bonded to a positively charged carbon

20
Q

Electrophile

A

An ion or molecule that attacks regions of high electron density

21
Q

Primary halogenoalkane

A

A halogenoalkane that has one carbon bonded directly to the carbon that is bonded to the halogen

22
Q

Heterolytic fission

A

Bond breaking in which both electrons in the shared pair go to a single atom

23
Q

Nucleophile

A

An ion or molecule, with a lone pair of electrons, that attacks regions of low electron density

24
Q

Elimination

A

A reaction in which a small molecule is removed from a larger molecule

25
Reflux
Repeated boiling and condensing of a reaction mixture
26
Hydrolysis
Breaking up molcules by the reaction with water
27
Primary alcohols
An alcohol which has one carbon bonded directly to the carbon that is bonded to the -OH group