ORGANIC DEFINITIONS Flashcards
Homologous series
Compounds which have
-The same general formula
-Similar chemical properties
-Show a gradation in physical properties
-And successive members differ by a CH2 unit
Hydrocarbon
Molecules which contain carbon and hydrogen only
Saturated hydrocarbon
Molecules which contain no C=C bonds
Structural isomers
Molecules which have the same molecular formula but different structural formula
Homolytic fission
Bond breaking in which one of the shared electrons goes to each atom
Free radical
A particle with an unpaired electron
Substitution
Replacing one atom or group with a different atom or group
Functional group
Reactive group within a compound ( C=C, OH, Cl etc)
Unsaturated
Molecules which contain at least one C=C bond or C triple bond C
Stereoisomers
Same structural formula but different arrangement of atoms in space
Geometric isomers
Same structural formula but different arrangement of atoms in space due to presence of at least one C=C
Sigma bond
A covalent bond formed by the linear overlap of atomic orbitals
Pi bond
Covalent bond formed by sideways overlap of p orbitals
Bond length
The distnace between the nuclei of two covalenty bonded atoms
Hydrogenation
Addition of hydrogen molecule across C=C
Monomers
Many small molecules which join together to form a polymer
Polymer
A large moleculeformed when monomers join together
Polymerisation
Joining togther of many small molecules to form a large molecule
Primary carbocation
Acarbocation which has one carbon atom directly bonded to a positively charged carbon
Electrophile
An ion or molecule that attacks regions of high electron density
Primary halogenoalkane
A halogenoalkane that has one carbon bonded directly to the carbon that is bonded to the halogen
Heterolytic fission
Bond breaking in which both electrons in the shared pair go to a single atom
Nucleophile
An ion or molecule, with a lone pair of electrons, that attacks regions of low electron density
Elimination
A reaction in which a small molecule is removed from a larger molecule