organic chemistry - stereochemistry Flashcards
what is an isomer?
two different molecules with the same number and type of atoms
what are structural isomers?
different bonding patterns
what are functional isomers?
structural isomers with the same molecular formula but different functional groups or moieties e.g. butan-1-ol and ethoxyethane (diethyl ether)
what are regional isomers?
structural isomers where the functional group changes position on the parent structure e.g. pentan-1-ol, pentan-2-ol etc.
what is a geometric isomer?
occurs when carbons in a ring are not able to rotate freely- substituents on the same side (Z isomers) or opposing sides (E isomers)
what is a stereoisomer?
different compounds with the same structure, differing only in the spatial organisation of the atoms
what is meant by chirality?
when a central carbon is bonded to four different groups - has no symmetry
what is a stereocentre?
an atom