Organic Chemistry Part 1 Flashcards

1
Q

What is a hydrocarbon?

A
  • molecules made of hydrogen and carbon atoms only
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2
Q

What is crude oil?

A
  • a finite resource found in rocks
  • remains of ancient biomass (mianly plankton buried in mud)
  • mixture of compounds- mostly hydrocarbons
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3
Q

What is crude oil processed to make?

A
  • fuels
  • feedstocks
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4
Q

What are feedstocks?

A
  • raw material for the petrochemical industry
  • mode into solvents, lubricants, polymers, detergents
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5
Q

Describe fractional distillation

A
  • crude oil heated, evaporated
  • vapour enters fractionating column (hot at bottom, cool at top)
  • molecules rise until they have cooled enough to condense
  • crude oil separated into different fractions with different boiling points
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6
Q

What is the realationship between the size of the molecules and where they condense on the fractionating column?

A
  • longer molecules = condense lower (hotter) in tower
  • smaller molecules = condense higher (cooler) in tower
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7
Q

How does the carbon chain length affect the molecules’ properties?

A
  • longer chain = higher boiling point
  • longer chain = more viscous
  • longer chain = less flammable
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8
Q

What is the general formula for an alkane?

A

Cn H2n+2

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9
Q

What are the names and formulas of the first four alkanes?

A

1) methane CH4
2) ethane C2H6
3) propane C3H8
4) butane C4H10

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10
Q

Name the fractions of crude oil from top to bottom

A
  • liquefied petrolium gases (fuels)
  • petrol (fuel for cars)
  • kerosene (aircraft fuel)
  • diesel (fuel for cars, buses, and lorries)
  • heavy fuel oil (fuel for ships or power stations)
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11
Q

What type of reaction is combustion with hydrocarbons?

A
  • oxidation
  • hydrogen and carbon gain oxygen, oxidised
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12
Q

What is the formula of the complete combustion of a hydrocarbon?

A

hydrocarbon + oxygen -> carbon dioxide + water

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13
Q

What is cracking?

A
  • breaking down long chain alkanes to produce smaller, more useful molecules
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14
Q

Why is cracking important?

A
  • long hydrocarbons have less demand, would be wasted otherwise
  • shorter chain molecules have more demand
  • alkenes used as feedstock for making polymers
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15
Q

What does cracking do?

in terms of bonds

A
  • break covalent bonds and forms new bonds
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16
Q

What happens during catalytic cracking?

A
  • long chain alkanes heated and vaporised
  • vapour passed over hot catalyst

450-550 C

17
Q

What happens during steam cracking?

A
  • long chian alkanes heated and vaporised
  • vapour mixed with steam
  • heated to very high temperature

750-900 C, high pressure

18
Q

What is the difference between an alkane and an alkene?

A
  • alkanes only have single bonds
  • alkenes have double bonds
19
Q

Draw and label a diagram of cracking in a lab

A
20
Q

What is the general formula for alkenes?

A
  • CnH2n
21
Q

How do you test for alkenes?

A
  • add few drops of bromine water to alkene
  • add stopper and shake
  • alkane = no change
  • alkene = orange-brown to colourless
  • alkenes are more reactive than alkanes