Organic Chemistry Part 1 Flashcards
What is a hydrocarbon?
- molecules made of hydrogen and carbon atoms only
What is crude oil?
- a finite resource found in rocks
- remains of ancient biomass (mianly plankton buried in mud)
- mixture of compounds- mostly hydrocarbons
What is crude oil processed to make?
- fuels
- feedstocks
What are feedstocks?
- raw material for the petrochemical industry
- mode into solvents, lubricants, polymers, detergents
Describe fractional distillation
- crude oil heated, evaporated
- vapour enters fractionating column (hot at bottom, cool at top)
- molecules rise until they have cooled enough to condense
- crude oil separated into different fractions with different boiling points
What is the realationship between the size of the molecules and where they condense on the fractionating column?
- longer molecules = condense lower (hotter) in tower
- smaller molecules = condense higher (cooler) in tower
How does the carbon chain length affect the molecules’ properties?
- longer chain = higher boiling point
- longer chain = more viscous
- longer chain = less flammable
What is the general formula for an alkane?
Cn H2n+2
What are the names and formulas of the first four alkanes?
1) methane CH4
2) ethane C2H6
3) propane C3H8
4) butane C4H10
Name the fractions of crude oil from top to bottom
- liquefied petrolium gases (fuels)
- petrol (fuel for cars)
- kerosene (aircraft fuel)
- diesel (fuel for cars, buses, and lorries)
- heavy fuel oil (fuel for ships or power stations)
What type of reaction is combustion with hydrocarbons?
- oxidation
- hydrogen and carbon gain oxygen, oxidised
What is the formula of the complete combustion of a hydrocarbon?
hydrocarbon + oxygen -> carbon dioxide + water
What is cracking?
- breaking down long chain alkanes to produce smaller, more useful molecules
Why is cracking important?
- long hydrocarbons have less demand, would be wasted otherwise
- shorter chain molecules have more demand
- alkenes used as feedstock for making polymers
What does cracking do?
in terms of bonds
- break covalent bonds and forms new bonds