Organic Chemistry of the F-Block Flashcards
1
Q
types of reactions
A
oxidation, reduction and used as LA
2
Q
cerium (IV) [O]
A
selectively oxidises secondary alcohols, phenol ethers to quinones and aromatics
3
Q
co-oxidant for Ce
A
NaBrO3 allows Ce to be used catalytically
4
Q
uses of Sm2+
A
radical and barbier reactions
5
Q
Ce3+ and 1,2 vs 1,4-cycloadditions
A
Ce3+ salts used with organolithium or NaBH4 to favour 1,2 over 1,4 additions
