organic chemistry introduction (organic) Flashcards
what is the empirical formula
the simplest ratio of atoms of each element in a compound
how do you work out the empirical formula
mass/atomic mass then divide by the smallest number
what is molecular formula
shows the actual amount of atoms of each element in a molecule. can be found using the empirical formula, relative molecular mass of the empirical formula and the relative mass of the molecule
what is a free radical
when a covalent bond breaks, one electron goes to each of the atoms that formed the original bond (represented by single headed curly arrows)
whats the functional group of an alkane
C-C
functional group of alkene
C=C
functional group of alcohol (hydroxyl)
OH
functional group of aldehydes
H-C=O
functional group of ketones
C=O
functional groups of carboxylic acids
HO-C=O
what does aliphatic mean
carbon atoms are arranged in an unbranched structure
what does alicylic mean
carbon atoms are arranged in a ring structure
what does aromatic mean
all or some carbons are found in a benzene ring
general formulas of alkanes, alkenes and alkynes
alkanes - CnH2n+2
alkenes - CnH2n
alkynes - CnH2n-2
suffix group of alkane
ane
suffix group of alkene
ene
suffix group of alcohol
ol
suffix group of aldehyde
al
suffix group of kentone
one
suffix group of carboxylic acid
oic acid
what happens as chain length increases
boiling point increases
what do curly arrows show
movement of electrons
what is an isomer?
molecules with the same molecular formula but a different arrangement of atoms
what is a structural isomer?
different structural arrangement of atoms - can be branched or straight chains
what is a positional isomer?
molecules have a functional group at a different position on the chain
what is a functional group isomer?
different arrangement of the same molecular formula so the molecule has a different functional group
what is a stereoisomer?
different spatial arrangement. e.g. E,Z isomerism
what is E,Z isomerism?
limited rotation around a double carbon bond can either be together or apart
what is the E isomer?
groups are apart - on different sides of the double bond
what is the Z isomer?
groups are together - on the same side of the double bond
what is chain isomerism
hydrocarbon chain organised differently (branched chain)