Organic Chemistry Flashcards

1
Q

True or false?
Alkanes generally undergo complete combustion.

A

True

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2
Q

True or false?
Alkanes generally undergo incomplete combustion.

A

False

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3
Q

True or false?
Alkenes generally undergo complete combustion.

A

False

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4
Q

True or false?
Alkenes generally undergo complete combustion.

A

True

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5
Q

What is a functional group?

A

A group of atoms in an organic molecule that determines its characteristics and reactions.

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6
Q

What is a homologous series?

A

A group of organic molecules that contain the same functional group.

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7
Q

What is an addition reaction? (2)

A

A reaction where new atoms are added, breaking the double bond in alkenes.

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8
Q

What are three uses of ethanol (alcohol)?

A

Alcoholic drinks
Solvents (e.g. perfumes)
Fuels (e.g. biofuels)

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9
Q

Why are alcohols a homologous series?

A

They all have the OH functional group.

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10
Q

What suffix do all alcohols end with?

A

-anol

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11
Q

What are the two ways of producing alcohol?

A
  1. Fermentation of glucose by yeast
  2. Reaction of ethene with water
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12
Q

What is the equation for fermentation of glucose by yeast?

A

Glucose -> Ethanol + carbon dioxide

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13
Q

What is the equation for the reaction of ethene with water?

A

Ethene + water -> ethanol

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14
Q

What is the other word for the reaction of ethene with water?

A

Hydration (think of water)

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15
Q

Is hydration a reversible reaction?

A

Yes

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16
Q

True or false? Hydration is a reversible reaction.

A

True

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17
Q

What temperature does hydration require?

A

300°C

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18
Q

What catalyst does hydration need?

A

70atm of phosphoric acid.

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19
Q

What are two advantages of hydration?

A
  1. Fast
  2. Produces a high yield of ethanol
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20
Q

For hydration, what does it requiring high temperature mean? Is this an advantage or disadvantage?

A

It requires lots of energy, which is a disadvantage.

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21
Q

What is a disadvantage of hydration?

A

Require a high temperature, which requires lots of energy.

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22
Q

The fact that the reaction of ethene with water comes from crude oil, what does this mean in terms of a disadvantage?

A

It is not renewable.

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23
Q

What temperature does the fermentation of glucose require?

A

Around 30°C

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24
Q

True or false? Fermentation of glucose must take place in anaerobic respiration?

A

True

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25
True or false? Fermentation of glucose must take place in aerobic respiration?
False
26
Does the fermentation of glucose have to take place in anaerobic respiration?
Yes
27
Are sugars renewable? If so, is this an advantage?
Yes, yes
28
What type of process is the fermentation of glucose?
Batch process
29
What two positives does the fermentation of glucose being a batch process bring about?
1. Cheaper equipment 2. Low temperature, so low energy
30
What are the four reactions of alcohols?
1. Hydration 2. Combustion 3. Exposure to sodium 4. Exposure to acidified potassium dichromate
31
Are alcohols soluble in water?
Yes
32
What type of solution do alcohols produce when water is added? (related to pH)
Neutral solution
33
When sodium is added to alcohols, what solution is produced?
Sodium ethoxide
34
What gas is produced when sodium is added to alcohols?
Hydrogen
35
Is the reaction of alcohols when sodium is added more or less vigorous than sodium and water?
Less vigorous as sodium and water.
36
What type of combustion do alcohols undergo?
Complete combustion
37
True or false? Alcohols undergo incomplete combustion.
False
38
True or false? Alcohols undergo complete combustion.
True
39
What is the other term for the oxidation of alcohols?
Exposure to acidified potassium dichromate.
40
What is the other term for the exposure to acidified potassium dichromate?
The oxidation of alcohols.
41
What acid does the oxidation of alcohols produce?
Carboxylic acids
42
Does microbial oxidation of ethanol produce a strong or weak solution? What is the name of the acid called?
Weak solution of a carboxylic acid called ethanoic acid.
43
What is the equation for the reaction of alcohols when exposed to acidified potassium dichromate?
ethanol + water → ethanoic acid + water
44
What four things do you add when drawing a diagram for a polymer from a monomer?
1. Brackets 2. Extension lines go through the brackets 3. 'n' in the bottom-right hand corner 4. Double bond becomes single bond
45
True or false? Alcohols is a homologous series.
True
46
What is the first alcohol?
Methanol
47
What is the second alcolhol?
Ethanol
48
What is the third alcohol?
Propanol
49
What is the fourth alcohol?
Butanol
50
For the displayed formula of alcohols, what do you add to it each time as you go down the table of alcohols?
C
51
What monomers are involved in addition addition polymerisation?
Alkenes
52
What type of bond do alkenes have?
C=C - Double carbon-to-carbon bond.
53
What monomers are involved in condensation polymerisation?
Monomers with two functional groups.
54
What are the two products of condensation polymerisation?
Polymer + water
55
What are the four polymers that we study?
Starch Cellulose Protein DNA
56
What is the term for glucose and fructose?
Monosaccharides
57
What is a monosaccharide?
A molecule made up of one sugar unit.
58
What are the two products of glucose and fructose after condensation polymerisation? (natural polymers)
Sucrose + H₂O
59
What are the three different products of glucose monomers after condensation polymerisation? (natural polymers)
Starch polymers + H₂O Cellulose polymers + H₂O
60
What is a disaccharide?
Molecule formed by two monosaccharides which are joined by a condensation reaction.
61
What is a polysaccharide?
Molecule made up of 3 or more repeating sugar monomers.
62
What is the formula for monosaccharides?
(CH₂O)ₙ
63
How many carbon atoms do monosaccharides usually have?
6 carbons
64
What is the other term used to describe 6 carbons?
Hexose sugars
65
True or false? Sucrose is a disaccharide.
True
66
True or false? Sucrose is a monosaccharide.
False
67
True or false? Sucrose is a polysaccharide.
False
68
What is the equation for natural polymers?
Glucose + fructose →(condensation reaction) sucrose + water
69
What do condensation reactions between monosaccharides make?
Polysaccharide chain
70
What is the equation for natural polymers - proteins?
amino acid monomers →(condensation reaction) protein polymers + H₂O
71
How many different functional groups do amino acids have in a molecule?
2
72
When amino acids react by condensation polymerisation, what is produced?
Polypeptides
73
When amino acids are joined together by condensation reactions, what three things are possibly formed?
Dipeptide Polypeptides Proteins
74
What are the two types of polysaccharides?
Starch Cellulose
75
What does starch form?
Forms branched chains of glucose monomers.
76
What does celluose form?
Forms straight chains of glucose monomers.
77
When straight chains of glucose monomers are lined up next to each other, what do they form?
Form strong fabric fibers.
78
Starch is compact. How is this good?
It is a great energy storage molecule in cells.
79
Why is cellulose good in plants?
Strong cell walls in plants.
80
What are proteins in terms of polypeptides?
Proteins are complex branched versions of polypeptides.
81
How are proteins formed?
Formed from a mixture of the 20 amino acids made in our bodies.
82
What can butane be used as? Formulation|Fuel
Fuel
83
Why is the potential yield of ethanol less than 100%? (2 possible reasons)
1. Some ethanol changes back into ethene and steam (reversible reaction). 2. Some ethanol escapes from the apparatus.
84
Complete the equation: ___ + steam ⇌ ethanol.
Ethene
85
True or False? The reaction of ethene and steam to produce ethanol is a reversible reaction.
True
86
What are two advantages of using fermentation to produce ethanol?
1. Low energy usage. 2. Raw material is sugar, which is renewable.
87
What are two disadvantages of using fermentation to produce ethanol?
1. Slow rate of reaction. 2. Produces impure ethanol.
88
Describe the test for the double carbon-carbon bond (C=C) in cycloalkenes (which act similarly to alkenes). Give the result of the test.
Test: React with bromine water. Result: Turns from orange to colourless.
89
What acid is ethanoic acid a weak solution of?
Carboxylic acids
90
CnH2n+2