Organic Chemistry Flashcards
Estimation of C
12/44 ×a/W ×100
Estimation of H
2/18 × b/W ×100
Estimation of Cl
35.5/143.5 × x/W ×100
Estimation of Br
80/188× x/W ×100
Estimation of I
127/235 × x/W × 100
Estimation of S
32/233 × x/W × 100
Estimation of P
62/222 × x/W × 100
Duma’s method of estimation of N
Kjeldah’s method can’t be used for
1.N in ring
2.Nitro compounds
3.Azo compounds
Kjeldah’s method
nNH3= 2(MaVa-MbVb/2)
% of NH3 =nNH3×14×100/x
where x is the mass of the organic compound
Duma’s method
P=Pgiven-aqueous Tension
n=PV/RT
%N=n×28×100/x
Aromatic compounds huckle’s rule
4n+2=π electron
Anti aromatic
4n=π electron
What is cis?
when two same atoms or group are in same plane
What is trans?
2 same atoms or groups are in different planes