Organic Chemistry Flashcards
Homologous series
A group of compounds with the same general formula and contain the same functional groups
Hydrocarbons
Organic compounds that contain hydrogen and carbon atoms only.
General formula of alkanes
CnH2n+2
General formula of alkenes
CnH2n
General formula of alkynes
CnH2n-2
Unsaturated compounds
Compounds that contain double or triple bonds between carbon atoms
Primary alcohol
Hydroxyl group is bonded to a carbon bonded to only one other carbon
Secondary alcohol
Hydroxyl group is bonded to a Carbon that is bonded to two other Carbons
Tertiary alcohol
Hydroxyl group is bonded to a Carbon bonded to three other Carbon atoms
Bromine water with alkenes vs alkanes
Unsaturated compounds discolour bromine water whereas saturated compounds do not.
Reaction conditions for Hydrohalogenation
No water may be present
Hydration
Alkene + water —> alcohol
Reaction conditions for Hydration
Excess water
Presence of a catalyst (Sulphuric acid)
Mild heat
Reaction conditions for Hydrogenation
Th addition of diatomic H atom
A catalyst (Pt, Ni, Pd)
Alkene must be dissolved in a non polar solvent
Dehydrohalogenation
Haloalkane —> alkene + metal halide + H20 (strong base)
Reaction conditions for Dehydrohalogenation
Heat under reflux
Concentrated strong base (NaOH)
Reaction conditions for Dehydration
An excess of a strong acid catalyst (H2SO4)
High temperatures
Reaction conditions for Cracking
High temperatures and pressures
Low temperature and pressure in the presence of a catalyst
Reaction conditions for Hydrolysis
mild heat
A dilute strong base (NaOH/KOH)
The solution must be aqueous
Reaction conditions for the formation of haloalkane from alkanes
Energy in the form of light (UV light)
Melting point
The temperature at which a substances solid and liquid states are in equilibrium
Boiling point
The temperature at which a substances vapour pressure is equal to atmospheric pressure
Vapour pressure
The pressure exerted by a substance in equilibrium with a solid or liquid in a closed container at a given temperature
Viscosity
The resistance of a fluid to flow or change its shape