Organic chemistry Flashcards

1
Q

saturated and unstaurated hydrocarbon

A

Saturated = single bonds only Unsaturated = contains carbon to carbon multiple bonds (double or triple)

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2
Q

Functional group

A

A group of atoms responsible for the characteristic reactions of a compound

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3
Q

Homologous series

A

A series of organic compounds having the same functional group but with each successive member differing by CH2

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4
Q

Structural isomers

A

Molecules that have the same molecular formula but different structural formula

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5
Q

aliphatic

A

a compound containing carbon and hydrogen joined together in straight chains, branched chains or non-aromatic rings

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6
Q

alicyclic

A

an aliphatic compound arranged in non-aromatc rings with or without side chains

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7
Q

aromatic

A

a compound containing a benzene ring

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8
Q

homolytic fission

A

each bonding atom receiving one electron from the bonded pair, forming two radicals

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9
Q

heterolytic fission

A

one bonding atom receiving both electrons from the bonded pair

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10
Q

sigma bond

A

an overlap of two orbitals, one from each bonding atom

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11
Q

free radical

A

an atom/group of atoms that have a single unpaired electron

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12
Q

pi bond

A

sideways overlap of adjacent p-orbitals above and below the bonding C atoms

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13
Q

stereoisomers

A

compounds with the same structural formula but with a different arrangement in space

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14
Q

E/Z isomerism

A

an example of stereoisomerism, in terms of restricted rotation about a double bond and the requirement for two diferent groups to be attached to each carbon atom of the C=C group

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15
Q

cis/trans isomerism

A

a special case of E/Z isomerism in which two of the substituent groups atached to each
carbon atom of the C=C group are the same

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16
Q

Electrophile

A

an electron pair acceptor