Organic Chemistry Flashcards

1
Q

What are some chemicals used to distinguish an aldehyde from a ketone?

A

Tollens reagent
Fehilinhs solution
Benedicts solution
Acidified Pottassium Dichromate

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2
Q

What colour change occurs when tollens reagent reacts with an aldehyde?

A

Silver mirror

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3
Q

What colour change occurs if Fehilings solution reacts with an aldehyde?

A

Blue to red

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4
Q

What colour change occurs if benedicts reacts with an aldehyde?

A

Blue to red

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5
Q

What colour change happens when Acidfied Pottassium Dichromate reacts with an aldehyde?

A

Orange to green

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6
Q

Does tollens reagent react with ketones?

A

No

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7
Q

Does tollens reagent react with aldehydes?

A

Yes

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8
Q

Does Fehilings solution react with aldehydes?

A

Yes

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9
Q

Does Fehilings solution react with ketones?

A

No

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10
Q

Does benedicts solution react with ketones?

A

No

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11
Q

Does benedicts solution react with aldehydes?

A

Yes

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12
Q

Does Acidfied Pottassium Dichromate react with ketones?

A

No

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13
Q

Does Acidfied Pottassium Dichromate react with aldehydes?

A

Yes

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14
Q

Is carbon dioxide symetical?

A

Yes

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15
Q

What reaction happens when a vegetable oil turns into a vegetable fat?

A

Hydrogenation

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16
Q

Can primary alcohols be oxidised?

A

Yes

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17
Q

What are primary alcohols oxidised into?

A

Aldehydes

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18
Q

Can aldehydes be oxidised?

A

Yes

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19
Q

What are aldehydes oxidised into?

A

Carboxylic acids

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20
Q

Can secondary alcohols be oxidised?

A

Yes

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21
Q

What are secondary alcohols oxidised into?

A

Ketones

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22
Q

Can ketones be oxidised?

A

No

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23
Q

Can tertiary alcohols be oxidised?

A

No

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24
Q

What is the molecular formula of isoprene?

A

C5H8

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25
What does meth mean?
1
26
What does eth mean?
2
27
What does prop mean?
3
28
What does but mean?
4
29
What does pent mean?
5
30
What does hex mean?
6
31
What does hept mean?
7
32
What does Oct mean?
8
33
What are isomers?
Isomers are compounds with the same molecular formulas but different structural formulas.
34
Are hydrocarbons polar?
No
35
What intermolecular forces do hydrocarbons contain?
London Dispersion Forces
36
Are alkanes saturated?
Yes
37
What is the general formula for alkanes?
CnH2n+1
38
What does saturated mean?
Only single carbon - carbon bonds
39
Are alkenes saturated?
No
40
What does unsaturated mean?
Contains a carbon - carbon double bond. | Can undergo addition reactions
41
What is the general formula for alkenes?
CnH2n
42
Are alkanes unsaturated?
No
43
Are alkenes unsaturated?
Yes
44
What functional groups do alkanols have?
Hydroxyl group
45
Are alkanols soluble in water?
Yes
46
How does increasing the molecular size of alkanols affect their solubility?
As size increases solubility in water decreases
47
What is a primary alcohol?
When the carbon bonded to the o-h group is bonded to one other carbon
48
What is a secondary alcohol?
When the carbon bonded to the o-h group is bonded to two other carbons
49
What is a tertiary alcohol?
When the carbon bonded to the o-h group is bonded to three other carbons
50
What is a diol?
An alcohol with two hydroxyl groups
51
What is a triol?
An alcohol with three hydroxyl groups
52
What is a trihydric acid?
An alcohol with 3 hydroxyl groups
53
What is Glycerols systematic name?
Propan-1,2,3-triol
54
What functional group do carboxylic acids have?
Carboxyl group
55
Can carboxylic acids be neutralised with bases?
Yes
56
What are bases?
Metal oxidises Metal hydroxides Metal carbonates
57
What functional groups do aldehydes contain?
Carbonyl group
58
What functional groups do ketones contain?
Carbonyl
59
How are esters formed?
Esters are formed from the condensation reaction between alcohols and carboxylic acids.
60
What are fats and oils?
Esters
61
Do fats or oils have higher melting points?
Fats
62
What is produced by the hydrolysis of a fat or oil?
3 moles of carboxylic acid to one mole of alcohol
63
Are oils more unsaturated than fats ?
Yes
64
What are soaps made from?
The alkaline hydrolysis of fats and oils
65
Soaps head is?
Ionic and hydrophilic
66
Soaps tail is?
Hydrophobic hydrocarbon chain that dissolves in oil
67
Are proteins polymers?
Yes
68
What are polymers?
Made up of smaller monomers
69
What monomers are proteins made up of?
Amino acids
70
What functional groups do amino acids contain?
Amino group | Carboxyl group
71
Proteins are broken up in a digestion process called...
Hydrolysis
72
What are terpenes?
Common compounds found in essential oils, based on units of isoprene joined together
73
How do you find the number of isoprene units in a terpene?
Count the carbons and divide by 5
74
How does saturation affect melting point?
The more saturated a molecule is the more hydrogen atoms it has, so the more saturated a molecule is the higher the melting point