Organic Chemistry 1 Flashcards

1
Q

Homologous Series

A

Name of organic chemical families. E.g alcohols is a homologous series. To be apart of a specific series the organic chemical has to have the same functional group

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2
Q

Functional Group

A

Specific atoms of an organic molecule that defines the properties and is the part that reacts with other molecules

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3
Q

Saturated

A

An organic molecule without the presence of a double bond

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4
Q

Unsaturated

A

An organic molecule with a double bond

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5
Q

Aliphatic Hydrocarbon

A

A hydrocarbon with carbon atoms joined together in a straight or branched chain

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6
Q

Alicyclic Hydrocarbon

A

Atoms of a hydrocarbon in a ring structure

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7
Q

Aromatic Hydrocarbons

A

Contain at least one benzene ring

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8
Q

Naming organic molecule rules

A
  1. The number of C atoms bonded together
  2. The presence of the functional group bonded to the C chain
  3. The position of the Functional group
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9
Q

General formula

A

Simplest algebraic formulae

Alkanes = Cn H 2n+2

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10
Q

Empirical Formula

A

The snakes while number ratio

Eg hexane = C3H7

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11
Q

Structural formula

A

Gives minimum detail of the arrangement

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12
Q

Molecular formula

A

Shows the numbers and types of stones in a compound

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13
Q

Displayed formula

A

Shows the positions and bonds of atoms

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14
Q

Skeletal formula

A

Lines to represent alkyl chains and every corner represents a carbon

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15
Q

Isomers

A

Molecules with the same molecule formula but arranged in different ways

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16
Q

Structural Isomers

A
  1. Positional
  2. Functional group
  3. Chain
17
Q

Positional

A

The skeleton and the functional group could be the same only with the functional group attached to a different carbon atom

18
Q

Functional Group (Isomer)

A

The same atoms can be arranged into different functional groups

19
Q

Chain (Isomers)

A

Carbon skeleton can be arranged differently

20
Q

Trends in boiling points of Alkanes

A

As alkane chain gets longer it’s relative molecular mass increases. Therefore more surface area contacts between adjacent molecules. This increase the number if induced dipole-dipole forces.

21
Q

Trends in boiling points of structural isomers

A

Structural isomers have different boiling points. The more branches a molecule has the less compact molecules can get. So less surface area contact so weaker forces. So lower boiling points

22
Q

Trans/Cis E/Z

A

When an alkene has two large mass bodies attached to the double bond. If they are opposite sides and the same it’s Trans if they’re opposite sides and different then it’s E. If they are sane side and the same then It’s Cis. If they are same side and different it’s Z

23
Q

Complete combustion

A

Hydrocarbon + oxygen = carbon dioxide + water

24
Q

Incomplete combustion

A

Hydrocarbon + Oxygen = 1. CO2 + H2O + CO

  1. CO2 + H2O + C
  2. CO2 + H2O + C + CO
25
Q

Radical Substitution

A

.Substitution reaction
.Takes place on gas or solutions
.only in the presence on UV light

26
Q

Initiation

A

UV light breaks the bonds equally. If it’s a molecule like Cl2 then it’s called homiletic fission. forming two radical chlorine atoms. (Radical very reactive)

27
Q

Propagation

A

Radical Chlorine atom meets a methane molecule. The radical takes a hydrogen from the methane to make HCl and a radical methane. The radical methane meets a Cl2. Taking a Cl to make 1-Chloromethane and a Radical Cl

28
Q

Termination

A
  1. Two radical Cl meets to make Cl2
  2. A radical Cl meets a Radical Methane to make 1-chloromethane
  3. Two radical methane’s meet to make ethane