Organic Chem Unit 1 (VOCABULARY) Flashcards

1
Q

Orbital

A

mathematical descriptions that chemists use to explain and predict the properties of atoms and molecules

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2
Q

Heisenberg Uncertainty Principals

A

never define exactly where the electron is; nevertheless, we can find the electron densities-the probability of finding the electron in a particular part of the orbital

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3
Q

Pauli Exclusion Principle

A

each orbital can hold a max of 2 electrons, provided the spins are paired

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4
Q

Aufbau Principle

A

how to build up the electron configuration of an atom’s ground state

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5
Q

Hund’s Rule

A

2 or more orbitals of the same energy, electrons go into different orbitals rather than pair up in the same orbital

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6
Q

Octet Rule

A

atoms transfer or share electrons in such a way as to attain a filled shell of electron

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7
Q

Ionic bond

A

transfer of 1 electron gives each atom 2 electrons

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8
Q

Covalent Bond

A

electrons are shared

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9
Q

Lewis Structure

A

visualize bonding in covalent molecules

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10
Q

Non-bonding electrons

A

valence electrons that are not shared between 2 atoms = lone pairs

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11
Q

Formal Charge

A

number of valence electrons - number of non-bonding - 1/2 total number of electrons shared in bonds

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12
Q

Molecular Dipole Moment

A

dipole moment of the molecule taken as a whole

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13
Q

Intermolecular Forces

A

the force that mediates interaction between molecules, including the electromagnetic forces of attraction between atoms and other types of neighboring particles.

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14
Q

Dipole - Dipole

A

2 negative ends or positive ends approach each other, they repel, but may turn themselves in a more stable positive negative orientation

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15
Q

London Dispersion

A

arise from temporary dipole moments

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16
Q

Hydrogen bonds

A

special type of dipole-dipole attraction when a hydrogen atom strongly boned to a more electronegative atom exists in the vicinity of another electronegative atom with a lone pair of electrons

17
Q

Like dissolves like

A

Similar molecules have the ability to interact with each other (polar-polar; nonpolar-nonpolar)

18
Q

Resonance Structures

A

they are not different compounds, just different ways of drawing the same compound - movement of electrons in a specific molecule

19
Q

Delocalized

A

electron in a molecule, ion or solid metal that are not associated with a single atom or covalent bond

20
Q

Resonance-Stablized

A

spreading the positive charge over 2 atoms makes the ion more stable than negative

21
Q

Major Contributor

A

more stable resonance form

22
Q

Minor Contributor

A

less stable resonance form.

23
Q

Electronegativity

A

An atoms tendency to attract bonded electrons in a covalently bonded compound