Organic Chem :( Flashcards

1
Q

Esterfication and the equation

A

Esterfication is when an alcohol and a carboxylic acid react together in the prescence of a strong acid to form an ester. Many esters have their own distinctive fruit smell. This equation is in an equilibrium

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2
Q

Tertiary structure of Amino acid

A

It’s overall 3D shape that forms as a result of folding and bonding back on itself.various bonds such as disulfide bridges, hydrogen bonds, dipole-dipole, disperson forces and ionic bonds cause this to occur

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3
Q
A

Esters(-oate)

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4
Q
A

Alkenes(-ene)

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5
Q

Define Amino acid

A

Amino acids are the building blocks of protein

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6
Q

Oxidation of a primary alcohol

A
  • Primary alcohol ->Aldehyde(limited Cr2O72-/H+ + cold)
  • Aldehyde->Carboxylic acid(Cr2O72-/H+ + heat or MnO4-/H+)
  • Primary alcohol->Carboxylic acid( MnO4-/H+ or XS Cr2O72-/H+ + heat)
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7
Q
A

Carboxylic acids (-oic)

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8
Q

B-pleated sheet

A

occur when sections of a-amino acid residues have small side chains. Such sections can fit closely alongside one another and become held together via hydrogen bonding

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9
Q

Condensation Polymerisation

A

The joining of individual monomers by the loss of small molecules: H20 or CO2

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10
Q

Oxidation of secondary alcohol

A
  • Secondary alcohol->Ketone(Cr2O72-/H+ or MnO4-/H+)
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11
Q

Define structural isomers

A

Molecules that have the same molecular formula but have different chemical and physical properties

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12
Q

Define Polymer

A

Polymers are very large molecules composed of small repeating structural units

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13
Q
A

Aldehydes(-al)

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14
Q

a-helix structure:

A

Held in place by hydrogen bonds between a lone pair of electrons from the Oxygen atom of C=O, and the polar hydrogen atom of an N-H group four peptide links away

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15
Q
A

Alchols (-ol/hydroxyl-)

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16
Q

Secondary Structure of Amino acid

A

The regular arrangement of various sections of the protein chain.

  • a-helix: a coiled section
  • B-pleated sheets: corrugated structures
17
Q

Define Primary structure of Amino acid

A

The specific sequence of individual a-amino acid residues. This is listed from the N-Terminus to the C-Terminus

18
Q
A

Ketones(-one)

19
Q

Oxidation of tertiary alcohol

A
  • Tertiary alcohol->No reaction
20
Q
A

Amides(-amide)

21
Q
A

Amines(-amine/amino-)

22
Q

Metal and Alcohol Reaction

A

2R–OH(l) + 2Na(s) → H2(g) + 2R–O- + 2Na+

23
Q

Esterfication decomposition reaction

A

Ester + H2O —>(H2SO4) carboxylic acid + alcohol

24
Q

Alkene + Water —>(H2SO4) ????

A

Alkene + H20—>(H2SO4) Alcohol