organic chem Flashcards

1
Q

what type of organic reaction occurs when chlorine and methane are mixed in the presence of uv light?

A

substitution

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2
Q

why is methanol very soluble in water?

A

because it is polar

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3
Q

name or give the formula for a reagant that could be used to oxidise a sample of methanol

A

sodium or potassium dichromate

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4
Q

define octane number?

A

the measure of the tendency of a fuel to resist knocking

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5
Q

define auto ignition?

A

the premature ignition of the petrol air mixture before normal ignition of the mixture

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6
Q

what compound has an octane number of 100?

A

2-2-4 trimethylpentane

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7
Q

what compound has an octane number of 0

A

heptane

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8
Q

what are heptane and 2-2-4 trimethylpentane called?

A

reference hydrocarbons

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9
Q

how can the octane number of a fuel be measured?

A

by comparing its performance with known mixtures of heptan and 2-2-4 trimethyl pentane

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10
Q

what is an aliphatic compound?

A

an organic compound that conssits of open chain carbon atoms and closed chain compounds .

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11
Q

what do we observe when preparing ethyne?

A

1 fizzing takes place in the flask and a white solid is formed
2 the flask gets warm
3 bubbles of gas begin collecting in the jar

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12
Q

when we burn ethyne what is observed?

A

a bright smoky flame with alot of soot being formed due to unburnt carbon

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13
Q

when we add bromine water/ kmno4 to ethyne what color change is observed?

A

from red to colourless

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14
Q

name 4 common ways of increasing the octane number of petrol?

A

isomerisation , catalytic cracking , dehydrocyclisation , adding oxygenates

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15
Q

define polymer?

A

long chain molecules made by joining many small molecules

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16
Q

what is an addition reaction

A

one in which two or more molecules react togethor to form a single molecule

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17
Q

redox reaction

A

when a primary alcohol reacts with an oxidising agent

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17
Q

define organic synthesis

A

the process of making organic compounds from simpler starting molecules

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17
Q

first step of pvc synthesis?

A

in the first step ethene reacts with chlorine making 1-2 dichloroethane

18
Q

second step of pvc synthesis

A

in the second step 1-2 dichloroethane is subjucted to thermal cracking removing an hcl molecule and leaving us with vinyl chloride

19
Q

State boyles law

A

Boyles law states that at constant temperatuee the volume of a fixed amount of gas is inversely proportional to its pressure

20
Q

State charles law

A

Charles law states that at constant pressure the volume of a fixed amount of gas is directly proportional to its temperature on the kelvin scale

21
Q

The molecular formula

A

The molecular formula for a compound shows the number and type of each atom present in the molecule

22
Q

Empirical formula

A

The formula showing the simplest whole number ratio of the numbers of diff atoms present in a molecule

23
Q

Define molarity

A

The number of moles per litre of solution

24
Q

Define a salt

A

The substance formed when the hydrogen ion in am acid is replaced by a metal

25
Q

Arrhenius definition of a strong acid

A

A substance that almost completely dissociates in water to give hydrogen ions

26
Q

Arrhenius definition of a weak acid

A

A substamce that only partially dissociates in water to give hydrogen ions

27
Q

Arrhenius definition of a base

A

A substance that dissacosiates in water to give oh ions

28
Q

Step 1 in finding water of crystillisation in hydrated sodium carbonate

A

The pipette burette and conical flask are washed with deionised water

29
Q

Step 2 in finding water of crystillisation in sodium catbonate

A

About 5g of sodium carbonate crystals are weighed out on a clock glass

30
Q

Step 3 of water of crystillisation in sodium carbonate

A

The crystals are dissolved in water and transferred to a 250cm3 volumetric flask

31
Q

What is a strong acid?

A

A good proton donor

32
Q

What is a strong base?

A

A strong base is a good proton acceptor

33
Q

Define electrolysis

A

The use of electricity to bring about a chemical reaction

34
Q

Define elctrolyte

A

A compound which when molten or dissolved in water will conduct electricity

35
Q

Define electroplating?

A

A process where electrolyiss is used to put a layer of one metal on the surface of another

36
Q

What is a galvanic cell?

A

A cell in which a chemical reaction results in the production of current

37
Q

What is an elimination reaction?

A

The reverse of an addition reaction removing a substrate

38
Q

Hess law

A

States that if a chemical reaction takes place in a number of stages the sum of the heat changes in the seperate stages is equal to if it was done in one stage

39
Q

Define condensation reaction?

A

A reaction in which two molecules combine to form a larger molecule with the loss of a smaller molecule

40
Q

Define steam distillation

A

A seperation process used to isolate compounds at temperatures below their decomposition temperature

41
Q

Substitution reaction definition

A

A reaction in which an atom or group of atoms is replaced by another atom or group of atoms

42
Q

To prepare a sample of soap key steps

A

1 Lard or sunflower oil is put in a quickfit flask

2 sodium hydroxide and ethanol are added to the flask

3 some anti bumping chips are added

43
Q

To study the reaction of ethanoic acid with sodium carbonate

A

1 Some sodium catbonate powder is placed in a boiling tube

2 some ethanoic acid solution is added to the sodium carbonate powder