Organic chem Flashcards
Boiling point
The temperature at which the vapour pressure of a substance equals atmospheric pressure. The stronger the intermolecular forces, the higher the boiling point
Melting point
The temperature at which the solid and liquid phases of a substance are at equilibrium. The stronger the intermolecular forces, the higher the melting point.
Vapour pressure
The pressure exerted by a vapour at equilibrium with its liquid in a closed system. The stronger the intermolecular forces, the lower the vapour pressure
Molecular formula
A chemical formula that indicates the element and numbers of each of the atoms in a molecule.
Example: C4H8O
Structural formula
A structural formula of a compound shows which atoms are attached to which within the molecule. Atoms are represented by their chemical symbols and lines are used to represent ALL the bonds that hold the atoms
together.
Condensed structural formula
This notation shows the way in which atoms are
bonded together in the molecule, but DOES NOT SHOW ALL bond lines.
Example: CH3CH2COCH3
Saturated compounds
Compounds in which there are no multiple bonds between C atoms in their hydrocarbon chains
Unsaturated compounds
Compounds with one or more multiple bonds between
C atoms in their hydrocarbon chains
Functional group
A bond or an atom or a group of atoms that determine(s) the physical and chemical properties of a group of organic compounds
Functional isomer
The same molecular formula, but different functional groups
Positional isomers
Same molecular formula, but different positions of the side chain, substituents or functional groups on the parent chain e.g.: 1-chloropropane and 2-chloropropane or but-2-ene and but-1-ene
Chain isomers
Same molecular formula, but different types of chains, e.g. butane and 2-methylpropane
Cracking
The chemical process in which longer chain hydrocarbon molecules are broken down to shorter more useful molecules.
Hydrocarbon
Organic compounds that consist of hydrogen and carbon only.
Homologous series
A series of organic compounds that can be described by the same general formula