Organic Flashcards

questions on year 2 organic chemistry

1
Q

What are 2 major classes of organic chemicals?

A

Aliphatic: Straight or branched chain organic substances.

Aromatic/arene: Includes one or more ring of six carbon atoms with delocalised bonding.

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2
Q

Benzene structure

1) What is the molecular formula of benzene?
2) Describe the structure of benzene.
3) Describe the orbitals involved, position and name.

A

1) C6H6
2) 6 carbon atoms in a hexagonal ring with one H atom bonded to each C atom.
3) 6 p orbitals are delocalised in a ring structure above and below the plane of the carbon atoms.

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3
Q

What is the carbon to carbon bonds like in a benzene ring?

A

The carbon to carbon bonds are the same and have a length between c-c Single bond and c=c double bond. It is a planar molecule.

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4
Q

Describe the electron arrangement in the benzene ring.

A

The six electrons in the pi bonds are delocalized and spread out over
the whole ring. Delocalized means not attached to a particular atom.

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5
Q

What is the H-C-C Bond angle in benzene?

A

120˚

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6
Q

The thermodynamics of benzene. What do you know about the enthalpy change of benzene compared to hexene to hexane? Can you draw an enthalpy diagram to show this?

A

Look at this:

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