Organic Flashcards

1
Q

What is crude oil?

A

Non-renewable fuel, made of hydrocarbons of different lengths

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2
Q

Describe the characteristics of alkanes.

A

Single carbon bond, saturated.

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3
Q

Why are alkanes saturated?

A

Because no more hydrogen atoms can be added to them.

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4
Q

What is the general formula of alkanes?

A

CnH2n+2

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5
Q

Describe the characteristics of alkenes.

A

Double bond, unsaturated.

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6
Q

Why are alkenes unsaturated?

A

More atoms can be added to the carbon atoms that are double bonded.

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7
Q

What is the general formula of alkenes?

A

CnH2n

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8
Q

What is the word formula for the combustion of alkenes?

A

Alkene + oxygen → carbon dioxide + water

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9
Q

What is the word equation for the hydrogenation of an alkene?

A

Alkene + hydrogen → alkane

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10
Q

What is hydrogenation?

A

Addition of hydrogen.

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11
Q

What reactions can alkenes undergo?

A

Combustion, hydrogenation, adding halogens.

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12
Q

What does a structural formula show?

A

The arrangement of atoms carbon by carbon, with hydrogens and functional groups attached after each one.

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13
Q

What is a hydrocarbon isomer?

A

A hydrocarbon with the same molecular formula but a different displayed and structural formula.

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14
Q

What types of reactions occur with organic compounds and hydrocarbons?

A

Substitution (alkanes only) and addition (alkenes only).

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15
Q

What is substitution of hydrocarbons?

A

Only involves alkanes. One functional group is replaced by another.

E.g. CH₄ + Cl₂ → CH₃Cl + HCl

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16
Q

What is addition of hydrocarbons?

A

Alkenes only. Two or more molecules join together to form a larger molecule.

E.g. ethene + steam → ethanol

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17
Q

What is fractional distillation?

A

Splitting hydrocarbon chains into groups based on their length

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18
Q

What happens to hydrocarbons as they get longer?

A

Its melting point increases, becomes less flammable, becomes darker, becomes more viscous.

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19
Q

What is crude oil?

A

A mixture of different hydrocarbons.

20
Q

What is the order of hydrocarbon fractions by chain length?

A

Refinery gases, gasoline, kerosene, diesel, fuel oil, bitumen.

21
Q

What is the use of refinery gases?

A

Bottled gas.

22
Q

What is the use of gasoline?

A

Fuel for cars.

23
Q

What is the use of kerosene?

A

Fuel for planes.

24
Q

What is the use of diesel?

A

Fuel for lorries.

25
What is the use of fuel oil?
Fuel for boats/ships.
26
What is the use of bitumen?
Road surfacing.
27
Explain how fractional distillation works.
Crude oil is separated by fractional distillation. Crude oil is heated to 350°C and evaporates. The gas enters a fractional distillation column and the temperature decreases as it rises. Fractions with higher boiling points condense and are collected nearer the bottom. Shorter chains rise higher before condensing.
28
What is the word formula for incomplete combustion of alkanes?
Alkane + oxygen → carbon monoxide + water
29
Why is carbon monoxide dangerous?
Haemoglobin in red blood cells binds more readily to carbon monoxide than oxygen, reducing the blood’s oxygen-carrying capacity.
30
What does the reaction between alkenes and halogens form?
Dihaloalkanes.
31
What happens during the reaction between alkenes and halogens?
The double bond breaks, allowing a halogen diatomic molecule to bond across the two carbon atoms.
32
How can you test for the presence of alkenes?
Add to bromine water. If a double bond is present, the solution turns from orange to colourless. If not, it stays orange.
33
What is the functional group of alcohols?
OH
34
Which methods are used to oxidise ethanol?
Complete combustion, microbial oxidation (reaction with oxygen in the air to form ethanoic acid), heating with potassium dichromate in dilute sulfuric acid to form ethanoic acid.
35
How can you manufacture ethanol?
React ethene with steam using a phosphoric acid catalyst at 300°C, ferment glucose anaerobically at 30°C.
36
What is the functional group of carboxylic acids?
COOH
37
How do carboxylic acids behave in reactions?
Similarly to normal acids, but slightly slower. They still react with metals and carbonates.
38
Which carboxylic acid does vinegar contain?
Ethanoic acid.
39
What is the functional group of esters?
COO
40
Give an example of a reaction that produces the ester ethyl ethanoate
Ethanoic acid + ethanol ⇌ ethyl ethanoate + water
41
What is the structural formula of ethyl ethanoate?
CH₃COOCH₂CH₃
42
What catalyst is required to form esters?
Sulfuric acid (usually).
43
Why is water produced in ester formation?
The OH group from the acid and an H from the alcohol form H₂O, leaving behind the COO group in the ester.
44
What does volatile mean?
Something that evaporates easily.
45
What are esters used for?
Food flavourings and perfumes.
46
Describe the experiment to produce ethyl ethanoate.
Mix equal volumes of carboxylic acid and alcohol in a flask. Add a catalyst of sulfuric acid. Submerge flask in a hot water bath and heat to a simmer. Collect ester from the flask.
47
How are addition polymers created?
By joining together many monomers in a chain.